Loading (50 kb)...'

(continued)
14 5.0E-01 1.3E+00 1.9E-01 9.4E-01
16 6.0E-01 1.4E+00 2.2E-01 1.1E+00
18 6.8E-01 1.6E+00 2.4E-01 1.2E+00
20 7.6E-01 1.8E+00 2.7E-01 1.3E+00
22 8.2E-01 1.9E+00 3.0E-01 1.5E+00
24 9.0E-01 2.1E+00 3.3E-01 1.6E+00
26 1.0E+00 2.4E+00 3.6E-01 1.8E+00
28 1.1E+00 2.7E+00 4.0E-01 2.0E+00
30 1.2E+00 3.0E+00 4.4E-01 2.2E+00
35 1.5E+00 3.7E+00 5.4E-01 2.7E+00
40 1.9E+00 4.6E+00 6.8E-01 3.4E+00
45 2.4E+00 5.4E+00 8.4E-01 4.2E+00
50 2.9E+00 6.8E+00 1.0E+00 5.0E+00
55 3.5E+00 8.4E+00 1.3E+00 6.4E+00
60 4.3E+00 1.0E+01 1.5E+00 7.8E+00
65 5.4E+00 1.3E+01 1.9E+00 9.6E+00
70 6.0E+00 1.4E+01 2.2E+00 1.1E+01
75 6.8E+00 1.6E+01 2.4E+00 1.2E+01
80 7.6E+00 1.8E+01 2.7E+00 1.3E+01
85 8.2E+00 2.0E+01 3.0E+00 1.5E+01
90 9.4E+00 2.3E+01 3.4E+00 1.7E+01
95 1.0E+01 2.5E+01 4.0E+00 1.9E+01
100 1.2E+01 2.8E+01 4.3E+00 2.1E+01
105 1.3E+01 3.2E+01 4.8E+00 2.4E+01
110 1.5E+01 3.5E+01 5.4E+00 2.7E+01
115 1.7E+01 4.0E+01 6.0E+00 3.0E+01
120 1.9E+01 4.4E+01 6.4E+00 3.3E+01

TABULAR OR GRAPHIC MATERIAL SET AT THIS POINT IS NOT DISPLAYABLE
TABULAR OR GRAPHIC MATERIAL SET AT THIS POINT IS NOT DISPLAYABLE
TABULAR OR GRAPHIC MATERIAL SET AT THIS POINT IS NOT DISPLAYABLE
TABULAR OR GRAPHIC MATERIAL SET AT THIS POINT IS NOT DISPLAYABLE

Note: Authority cited: Sections 25150, 25159, 25159.5, 25245, 58004 and 58012, Health and Safety Code. Reference: Sections 25159 and 25159.5, Health and Safety Code; and 40 CFR part 266, Appendix I.





Appendix II -Tier I Feed Rate Screening Limits for Total Chlorine
Noncomplex Terrain Complex Terrain
Terrain Urban (g/hr) Rural (g/hr) (g/hr)
adjusted
eff. stack. ht. (m)
4 8.2E + 01 4.2E + 01 1.9E + 01
6 9.1E + 01 4.8E + 01 2.8E + 01
8 1.0E + 02 5.3E + 01 4.1E + 01
10 1.2E + 02 6.2E + 01 5.8E + 01
12 1.3E + 02 7.7E + 01 7.2E + 01
14 1.5E + 02 9.1E + 01 9.1E + 01
16 1.7E + 02 1.2E + 02 1.1E + 02
18 1.9E + 02 1.4E + 02 1.2E + 02
20 2.1E + 02 1.8E + 02 1.3E + 02
22 2.4E + 02 2.3E + 02 1.4E + 02
24 2.7E + 02 2.9E + 02 1.6E + 02
26 3.1E + 02 3.7E + 02 1.7E + 02
28 3.5E + 02 4.7E + 02 1.9E + 02
30 3.9E + 02 5.8E + 02 2.1E + 02
35 5.3E + 02 9.6E + 02 2.6E + 02
40 6.2E + 02 1.4E + 03 3.3E + 02
45 8.2E + 02 2.0E + 03 4.0E + 02
50 1.1E + 03 2.6E + 03 4.8E + 02
55 1.3E + 03 3.5E + 03 6.2E + 02
60 1.6E + 03 4.6E + 03 7.7E + 02
65 2.0E + 03 6.2E + 03 9.1E + 02
70 2.3E + 03 7.2E + 03 1.1E + 03
75 2.5E + 03 8.6E + 03 1.2E + 03
80 2.9E + 03 1.0E + 04 1.3E + 03
85 3.3E + 03 1.2E + 04 1.4E + 03
90 3.7E + 03 1.4E + 04 1.6E + 03
95 4.2E + 03 1.7E + 04 1.8E + 03
100 4.8E + 03 2.1E + 04 2.0E + 03
105 5.3E + 03 2.4E + 04 2.3E + 03
110 6.2E + 03 2.9E + 04 2.5E + 03
115 7.2E + 03 3.5E + 04 2.8E + 03
120 8.2E + 03 4.1E + 04 3.2E + 03


Note: Authority cited: Sections 25150, 25159, 25159.5, 25245, 58004 and 58012, Health and Safety Code. Reference: Sections 25159 and 25159.5, Health and Safety Code; and 40 CFR part 266, Appendix II.





Appendix III. -Tier II Emission Rate Screening Limits for Free Chlorine and Hydrogen Chloride
-------------------------------------------------------------------------------
Terrain-adjusted Monocomplex terrain Complex terrain
effective stack
height (m)
-------------------------------------------------------------------------------
Values for urban Values for rural Values for use in
areas areas urban & rural
areas
-----------------------------------------------------------
C12 HC: C12 HC: C12 HC:
(g/hr) (g/hr) (g/hr) (g/hr) (g/hr) (g/hr)
-------------------------------------------------------------------------------
4 8.2E+01 1.4E+03 4.2E+01 7.3E+02 1.9E+01 3.3E+02
6 9.1E+01 1.6E+03 4.8E+01 8.3E+02 2.8E+01 4.8E+02
8 1.0E+02 1.8E+03 5.3E+01 9.2E+02 4.1E+01 7.1E+02
10 1.2E+02 2.0E+03 6.2E+01 1.1E+03 5.8E+01 1.0E+03
12 1.3E+02 2.3E+03 7.7E+01 1.3E+03 7.2E+01 1.3E+03
14 1.5E+02 2.6E+03 9.1E+01 1.6E+03 9.1E+01 1.6E+03
16 1.7E+02 2.9E+03 1.2E+02 2.0E+03 1.1E+02 1.8E+03
18 1.9E+02 3.3E+03 1.4E+02 2.5E+03 1.2E+02 2.0E+03
20 2.1E+02 3.7E+03 1.8E+02 3.1E+03 1.3E+02 2.3E+03
22 2.4E+02 4.2E+03 2.3E+02 3.9E+03 1.4E+02 2.4E+03
24 2.7E+02 4.8E+03 2.9E+02 5.0E+03 1.6E+02 2.8E+03
26 3.1E+02 5.4E+03 3.7E+02 6.5E+03 1.7E+02 3.0E+03
28 3.5E+02 6.0E+03 4.7E+02 8.1E+03 1.9E+02 3.4E+03
30 3.9E+02 6.9E+03 5.8E+02 1.0E+04 2.1E+02 3.7E+03
35 5.3E+02 9.2E+03 9.6E+02 1.7E+04 2.6E+02 4.5E+03
40 6.2E+02 1.1E+04 1.4E+03 2.5E+04 3.3E+02 5.7E+03
45 8.2E+02 1.4E+04 2.0E+03 3.5E+04 4.0E+02 7.0E+03
50 1.1E+03 1.8E+04 2.6E+03 4.6E+04 4.8E+02 8.4E+03
55 1.3E+03 2.3E+04 3.5E+03 6.1E+04 6.2E+02 1.1E+04
60 1.6E+03 2.9E+04 4.6E+03 8.1E+04 7.7E+02 1.3E+04
65 2.0E+03 3.4E+04 6.2E+03 1.1E+06 9.1E+02 1.6E+04
70 2.3E+03 3.9E+04 7.2E+03 1.3E+06 1.1E+03 1.8E+04
75 2.5E+03 4.5E+04 8.6E+03 1.5E+06 1.2E+03 2.0E+04
80 2.9E+03 5.0E+04 1.0E+04 1.8E+06 1.3E+03 2.3E+04
85 3.3E+03 5.8E+04 1.2E+04 2.2E+06 1.4E+03 2.5E+04
90 3.7E+03 6.6E+04 1.4E+04 2.5E+06 1.6E+03 2.9E+04
95 4.2E+03 7.4E+04 1.7E+04 3.0E+06 1.8E+03 3.2E+04
100 4.8E+03 8.4E+04 2.1E+04 3.6E+06 2.0E+03 3.5E+04
105 5.3E+03 9.2E+04 2.4E+04 4.3E+06 2.3E+03 3.9E+04
110 6.2E+03 1.1E+06 2.9E+04 5.1E+06 2.6E+03 4.5E+04
115 7.2E+03 1.3E+06 3.5E+04 6.1E+06 2.8E+03 5.0E+04
120 8.2E+03 1.4E+06 4.1E+04 7.2E+06 3.2E+03 5.6E+04
-------------------------------------------------------------------------------


Note: Authority cited: Sections 25150, 25159, 25159.5, 25245, 58004 and 58012, Health and Safety Code. Reference: Sections 25159 and 25159.5, Health and Safety Code; and 40 CFR part 266, Appendix III.





Appendix IV. -Reference Air Concentrations [FNa1]
------------------------------------------------------------
Constituent CAS No. RAC (ug/m<>3)
------------------------------------------------------------
Acetaldehyde 75-07-0 10
Acetonitrile 75-05-8 10
Acetophenone 98-86-2 100
Acrolein 107-02-8 20
Aldicarb 116-06-3 1
Aluminum Phosphide 20859-73-8 0.3
Allyl Alcohol 107-18-6 5
Antimony 7440-36-0 0.3
Barium 7440-39-3 50
Barium Cyanide 542-62-1 50
Bromomethane 74-83-9 0.8
Calcium Cyanide 592-01-8 30
Carbon Disulfide 75-15-0 200
Chloral 75-87-6 2
Chlorine (free) 0.4
2-Chloro-1,3-butadiene 126-99-8 3
Chromium III 16065-83-1 1000
Copper Cyanide 544-92-3 5
Cresols 1319-77-3 50
Cumene 98-82-8 1
Cyanide (free) 57-12-15 20
Cyanogen 460-19-5 30
Cyanogen Bromide 506-68-3 80
Di-n-butyl Phthalate 84-74-2 100
o-Dichlorobenzene 95-50-1 10
p-Dichlorobenzene 106-46-7 10
Dichlorodifluoromethane 75-71-8 200
2,4-Dichlorophenol 120-83-2 3
Diethyl Phthalate 84-66-2 800
Dimethoate 60-51-5 0.8
2,4-Dinitrophenol 51-28-5 2
Dinoseb 88-85-7 0.9
Diphenylamine 122-39-4 20
Endosulfan 115-29-1 0.05
Endrin 72-20-8 0.3
Fluorine 7782-41-4 50
Formic Acid 64-18-6 2000
Glycidyaldehyde 765-34-4 0.3
Hexachlorocyclopentadiene 77-47-4 5
Hexachlorophene 70-30-4 0.3
Hydrocyanic Acid 74-90-3 20
Hydrogen Chloride 7647-01-1 7
Hydrogen Sulfide 7783-06-4 3
Isobutyl Alcohol 78-83-1 300
Lead 7439-92-1 0.09
Maleic Anyhdride 108-31-6 100
Mercury 7439-97-6 0.3
Methacrylonitrile 126-98-7 0.1
Methomyl 16752-77-5 20
Methoxychlor 72-43-5 50
Methyl Chlorocarbonate 79-22-1 1000
Methyl Ethyl Ketone 78-93-3 80
Methyl Parathion 298-00-0 0.3
Nickel Cyanide 557-19-7 20
Nitric Oxide 10102-43-9 100
Nitrobenzene 98-95-3 0.8
Pentachlorobenzene 608-93-5 0.8
Pentachlorophenol 87-86-5 30
Phenol 108-95-2 30
M-Phenylenediamine 108-45-2 5
Phenylmercuric Acetate 62-38-4 0.075
Phosphine 7803-51-2 0.3
Phthalic Anhydride 85-44-9 2000
Potassium Cyanide 151-50-8 50
Potassium Silver Cyanide 506-61-6 200
Pyridine 110-86-1 1
Selenious Acid 7783-60-8 3
Selenourea 630-10-4 5
Silver 7440-22-4 3
Silver Cyanide 506-64-9 100
Sodium Cyanide 143-33-9 30
Strychnine 57-24-9 0.3
1,2,4,5-Tetrachlorobenzene 95-94-3 0.3
2,3,4,6-Tetrachlorophenol 58-90-2 30
Tetraethyl Lead 78-00-2 0.0001
Tetrahydrofuran 109-99-9 10
Thallic Oxide 1314-32-5 0.3
Thallium 7440-28-0 0.5
Thallium (I) Acetate 563-68-8 0.5
Thallium (I) Carbonate 6533-73-9 0.3
Thallium (I) Chloride 7791-12-0 0.3
Thallium (I) Nitrate 10102-45-1 0.5
Thallium Selenite 12039-52-0 0.5
Thallium (I) Sulfate 7446-18-6 0.075
Thiram 137-26-8 5
Toluene 108-88-3 300
1,2,4-Trichlorobenzene 120-82-1 20
Trichloromonofluoromethane 75-69-4 300
2,4,5-Trichlorophenol 95-95-4 100
Vanadium Pentoxide 1314-62-1 20
Warfarin 81-81-2 0.3
Xylenes 1330-20-7 80
Zinc Cyanide 557-21-1 50
Zinc Phosphide 1314-84-7 0.3
------------------------------------------------------------

[FNa1] The RAC for other appendix VIII chapter 11 constituents not listed herein or in appendix V of this chapter is 0.1 ug/m<>3.

Note: Authority cited: Sections 25150, 25159, 25159.5, 25245, 58004 and 58012, Health and Safety Code. Reference: Sections 25159 and 25159.5, Health and Safety Code; and 40 CFR part 266, Appendix IV.





Appendix V. -Risk Specific Doses (10-5)
-------------------------------------------------------------------------------
Unit
-------------------------------------------------------------------------------
Constituent CAS No. risk (m< >>3/ug) (ug/m<>3)
Acrylamide 79-06-1 1.3E-03 7.7E-03
Acrylonitrile 107-13-1 6.8E-05 1.5E-01
Aldrin 309-00-2 4.9E-03 2.0E-03
Aniline 62-53-3 7.4E-06 1.4E+00
Arsenic 7440-38-2 4.3E-03 2.3E-03
Benz(a)anthracene 56-55-3 8.9E-04 1.1E-02
Benxene 71-43-2 8.3E-06 1.2E+00
Benzidine 92-87-5 6.7E-02 1.5E-04
Benz(a)pyrene 50-32-8 3.3E-03 3.0E-03
Beryllium 7440-41-7 2.4E-03 4.2E-03
Bis(2-chloroethyl)ether 111-44-4 3.3E-04 3.0E-02
Bis(chloromethyl)ether 542-88-1 6.2E-02 1.6E-04
Bis(2-ethylhexyl)-phthalate 117-81-7 2.4E-07 4.2E+01
1,3-Butadiene 106-99-0 2.8E-04 3.6E-02
Cadmium 7440-43-9 1.8E-03 5.6E-03
Carbon Tetrachloride 56-23-5 1.5E-05 6.7E-01
Chlordane 57-74-9 3.7E-04 2.7E-02
Chloroform 67-66-3 2.3E-05 4.3E-01
Chloromethane 74-87-3 3.6E-06 2.8E+00
Chromium VI 7440-47-3 1.2E-02 8.3E-04
DDT 50-29-3 9.7E-05 1.0E-01
Dibenz(a,h)anthracene 53-70-3 1.4E-02 7.1E-04
1,2-Dibromo-3-chloropropane 96-12-8 6.3E-03 1.6E-03
1,2-Dibromoethane 106-93-4 2.2E-04 4.5E-02
1,1-Dichloroethane 75-34-3 2.6E-05 3.8E-01
1,2-Dichloroethane 107-06-2 2.6E-05 3.8E-01
1,1-Dichloroethylene 75-35-4 5.0E-05 2.0E-01
1,3-Dichloropropene 542-75-6 3.5E-01 2.9E-05
Dieldrin 60-57-1 4.6E-03 2.2E-03
Diethylstilbestrol 56-33-1 1.4E-01 7.1E-05
Dimethylnitrosamine 62-75-9 1.4E-02 7.1E-04
2,4-Dinitrotoluene 121-14-2 8.8E-05 1.1E-01
1,2-Diphenylhydrazine 122-66-7 2.2E-04 4.5E-02
1,4-Dioxane 123-91-1 1.4E-06 7.1E+00
Epichlorohydrin 106-89-8 1.2E-06 8.3E+00
Ethylene Oxide 75-21-8 1.0E-04 1.0E-01
Ethylene Dibromide 106-93-4 2.2E-04 4.5E-02
Formaldehyde 50-00-0 1.3E-05 7.7E-01
Heptachlor 76-44-8 1.3E-03 7.7E-03
Heptachlor Epoxide 1024-57-3 2.6E-03 3.8E-03
Hexachlorobenzene 118-74-1 4.9E-04 2.0E-02
Hexachlorobutadiene 87-68-3 2.0E-05 5.0E-01
Alpha-hexachloro-cyclohexane 319-84-6 1.8E-03 5.6E-03
Beta-hexachloro-cyclohexane 319-85-7 5.3E-04 1.9E-02
Gamma-hexachloro-cyclohexane 58-89-9 3.8E-04 2.6E-02
Hexachlorocyclohexane,
Technical 5.1E-04 2.0E-02
Hexachlorodibenxo-p-dioxin(1,2 1.3E+0 7.7E-06
Mixture)
Hexachloroethane 67-72-1 4.0E-06 2.5E+00
Hydrazine 302-01-2 2.9E-03 3.4E-03
Hydrazine Sulfate 302-01-2 2.9E-03 3.4E-03
3-Methycholanthrene 56-49-5 2.7E-03 3.7E-03
Methyl Hydrazine 60-34-4 3.1E-04 3.2E-02
Methylene Chloride 75-09-2 4.1E-06 2.4E+00
4,4 ' -Methylene-bis-2-
chloroaniline 101-14-4 4.7E-05 2.1E-01
Nickel 7440-02-0 2.4E-04 4.2E-02
Nickel Refinery Dust 7440-02-0 2.4E-04 4.2E-02
Nickel Subsulfide 12035-72-2 4.8E-04 2.1E-02
2-Nitropropane 79-46-9 2.7E-02 3.7E-04
N-Nitroso-n-butylamine 924-16-3 1.6E-03 6.3E-03
N-Nitroso-n-methylurea 684-93-5 8.6E-02 1.2E-04
N-Nitrosodiethylamine 55-18-5 4.3E-02 2.3E-04
N-Nitrosopyrrolidine 930-55-2 6.1E-04 1.6E-02
Pentachloronitrobenzene 82-68-8 7.3E-05 1.4E-01
PCBs 1336-36-3 1.2E-03 8.3E-03
Pronamide 23950-58-5 4.6E-06 2.2E+00
Reserpine 50-55-5 3.0E-03 3.3E-03
2,3,7,8-Tetrachloro-dibenzo-
p-dioxin 1746-01-6 4.5E+01 2.2E-07
1,1,2,2-Tetrachloroethane 79-34-5 5.8E-05 1.7E-01
Tetrachloroethylene 127-18-4 4.8E-07 2.1E-+01
Thiourea 62-56-6 5.5E-04 1.8E-02
1,1,2-Trichloroethane 79-00-5 1.6E-05 6.3E-01
Trichloroethylene 79-01-6 1.3E-06 7.7E-+00
2,4,6-Trichlorophenol 88-06-2 5.7E-06 1.8E+00
Toxaphene 8001-35-2 3.2E-04 3.1E-02
Vinyl Chloride 75-01-4 7.1E-06 1.4E+00


Note: Authority cited: Sections 25150, 25159, 25159.5, 25245, 58004 and 58012, Health and Safety Code. Reference: Sections 25159 and 25159.5, Health and Safety Code; and 40 CFR part 266, Appendix V.






Appendix VI. -Stack Plume Rise
[Estimated Plume Rise (in Meters) Based on Stack Exit Flow and Gas Temperature]

-------------------------------------------------------------------------------
Exhaust
Temperature (K
°)
Flow rate <3 325- 350- 400- 450- 500- 600- 700- 800- 1000- >1499
(m<>3 /s) 25 349 399 449 499 599 699 799 999 1499
-------------------------------------------------------------------------------
<0.5 0 0 0 0 0 0 0 0 0 0 0
0.5-0.9 0 0 0 0 0 0 0 0 1 1 1
1.0-1.9 0 0 0 0 1 1 2 3 3 3 4
2.0-2.9 0 0 1 3 4 4 6 6 7 8 9
3.0-3.9 0 1 2 5 6 7 9 10 11 12 13
4.0-4.9 1 2 4 6 8 10 12 13 14 15 17
5.0-7.4 2 3 5 8 10 12 14 16 17 19 21
7.5-9.9 3 5 8 12 15 17 20 22 22 23 24
10.0-12.4 4 6 10 15 19 21 23 24 25 26 27
12.5-14.9 4 7 12 18 22 23 25 26 27 28 29
15.0-19.9 5 8 13 20 23 24 26 27 28 29 31
20.0-24.9 6 10 17 23 25 27 29 30 31 32 34
25.0-29.9 7 12 20 25 27 29 31 32 33 35 36
30.0-34.9 8 14 22 26 29 31 33 35 36 37 39
35.0-39.9 9 16 23 28 30 32 35 36 37 39 41
40.0-49.9 10 17 24 29 32 34 36 38 39 41 42
50.0-59.9 12 21 26 31 34 36 39 41 42 44 46
60.0-69.9 14 22 27 33 36 39 42 43 45 47 49
70.0-79.9 16 23 29 35 38 41 44 46 47 49 51
80.0-89.9 17 25 30 36 40 42 46 48 49 51 54
90.0-99.9 19 26 31 38 42 44 48 50 51 53 56
100.0-119.9 21 26 32 39 43 46 49 52 53 55 58
120.0-139.9 22 28 35 42 46 49 52 55 56 59 61
140.0-159.9 23 30 36 44 48 51 55 58 59 62 65
160.0-179.9 25 31 38 46 50 54 58 60 62 65 67
180.0-199.9 26 32 40 48 52 56 60 63 65 67 70
>199.9 26 33 41 49 54 58 62 65 67 69 73



Note: Authority cited: Sections 25150, 25159, 25159.5, 25245, 58004 and 58012, Health and Safety Code. Reference: Sections 25159 and 25159.5, Health and Safety Code; and 40 CFR part 266, Appendix VI.





Appendix VII. -Health-Based Limits for Exclusion of Waste-Derived Residues [FNa1]
Metals-TCLP Extract Concentration Limits
-------------------------------------
Concentration
Constituent CAS No. Limits (mg/L)
-------------------------------------
Antimony 7440-36-0 1xE+00
Arsenic 7440-38-2 5xE+00
Barium 7440-39-3 1xE+02
Beryllium 7440-41-7 7xE-03
Cadmium 7440-43-9 1xE+00
Chromium 7440-47-3 5xE+00
Lead 7439-92-1 5xE+00
Mercury 7439-97-6 2xE-01
Nickel 7440-02-0 7xE+01
Selenium 7782-49-2 1xE+00
Silver 7440-22-4 5xE+00
Thallium 7440-28-0 7xE+00
-------------------------------------

Nonmetals-Residue Concentration Limits
----------------------------------------------------------------------
Concentration
Constituent CAS No. Limits for
----------------------------------------------------------------------
residues (mg/kg)
Acetonitrile 75-05-8 2xE-01
Acetophenone 98-86-2 4xE+00
Acrolein 107-02-8 5xE-01
Acrylamide 79-06-1 2xE-04
Acrylonitrile 107-13-1 7xE-04
Aldrin 309-00-2 2xE-05
Allyl alcohol 107-18-6 2xE-01
Aluminum phosphide 20859-73-8 1xE-02
Aniline 62-53-3 6xE-02
Barium cyanide 542-62-1 1xE+00
Benz(a)anthracene 56-55-3 1xE-04
Benzene 71-43-2 5xE-03
Benzidine 92-87-5 1xE-06
Bis(2-chloroethyl) ether 111-44-4 3xE-04
Bis(chloromethyl) ether 542-88-1 2xE-06
Bis(2-ethylhexyl) phthalate 117-81-7 3xE+01
Bromoform 75-25-2 7xE-01
Calcium cyanide 592-01-8 1xE-06
Carbon disulfide 75-15-0 4xE+00
Carbon tetrachloride 56-23-5 5xE-03
Chlordane 57-74-9 3xE-04
Chlorobenzene 108-90-7 1xE+00
Chloroform 67-66-3 6xE-02
Copper cyanide 544-92-3 2xE-01
Cresols (Cresylic acid) 1319-77-3 2xE+00
Cyanogen 460-19-5 1xE+00
DDT 50-29-3 1xE-03
Dibenz(a,h)-anthracene 53-70-3 7xE-06
1,2-Dibromo-3-chloropropane 96-12-8 2xE-05
p-Dichlorobenzene 106-46-7 7.5xE-02
Dichlorodifluoromethane 75-71-8 7xE+00
1,1-Dichloroethylene 75-35-4 5xE-03
2,4-Dichlorophenol 120-83-2 1xE-01
1,3-Dichloropropene 542-75-6 1xE-03
Dieldrin 60-57-1 2xE-05
Diethyl phthalate 84-66-2 3xE+01
Diethylstilbesterol 56-53-1 7xE-07
Dimethoate 60-51-5 3xE-02
2,4-Dinitrotoluene 121-14-2 5xE-04
Diphenylamine 122-39-4 9xE-01
1,2-Diphenylhydrazine 122-66-7 5xE-04
Endosulfan 115-29-7 2xE-03
Endrin 72-20-8 2xE-04
Epichlorohydrin 106-89-8 4xE-02
Ethylene dibromide 106-93-4 4xE-07
Ethylene oxide 75-21-8 3xE-04
Fluorine 7782-41-4 4xE+00
Formic acid 64-18-6 7xE+01
Heptachlor 76-44-8 8xE-05
Concentration
Constituent CAS No. Limits (mg/kg)
Heptachlor epoxide 1024-57-3 4xE-05
Hexachlorobenzene 118-74-1 2xE-04
Hexachlorobutadiene 87-68-3 5xE-03
Hexachlorocyclopentadiene 77-47-4 2xE-01
Hexachlorodibenzo-p-dioxins 19408-74-3 6xE-08
Hexachloroethane 67-72-1 3xE-02
Hydrazine 302-01-1 1xE-04
Hydrogen cyanide 74-90-8 7xE-05
Hydrogen sulfide 7783-06-4 1xE-06
Isobutyl alcohol 78-83-1 1xE+01
Methomyl 16752-77-5 1xE+00
Methoxychlor 72-43-5 1xE-01
3-Methylcholanthrene 56-49-5 4xE-05
4,4 ' -Methylenebis (2-chloroaniline) 101-14-4 2xE-03
Methylene chloride 75-09-2 5xE-02
Methyl ethyl ketone (MEK) 78-93-3 2xE+00
Methyl hydrazine 60-34-4 3xE-04
Methyl parathion 298-00-0 2xE-02
Naphthalene 91-20-3 1xE+01
Nickel cyanide 557-19-7 7xE-01
Nitric oxide 10102-43-9 4xE+00
Nitrobenzene 98-95-3 2xE-02
N-Nitrosodi-n-butylamine 924-16-3 6xE-05
N-Nitrosodiethylamine 55-18-5 2xE-06
N-Nitroso-N-methylurea 684-93-5 1xE-07
N-Nitrosopyrrolidine 930-55-2 2xE-04
Pentachlorobenzene 608-93-5 3xE-02
Pentachloronitrobenzene (PCNB) 82-68-8 1xE-01
Pentachlorophenol 87-86-5 1xE+00
Phenol 108-95-2 1xE+00
Phenylmercury acetate 62-38-4 3xE-03
Phosphine 7803-51-2 1xE-02
Polychlorinated biphenyls, N.O.S. 1336-36-3 5xE-05
Potassium cyanide 151-50-8 2xE+00
Potassium silver cyanide 506-61-6 7xE+00
Pronamide 23950-58-5 3xE+00
Pyridine 110-86-1 4xE-02
Reserpine 50-55-5 3xE-05
Selenourea 630-10-4 2xE-01
Silver cyanide 506-64-9 4xE+00
Sodium cyanide 143-33-9 1xE+00
Strychnine 57-24-9 1xE-02
1,2,4,5-Tetrachlorobenzene 95-94-3 1xE-02
1,1,2,2-tetrachloroethane 79-34-5 2xE-03
Tetrachloroethylene 127-18-4 7xE-01
2,3,4,6-Tetrachlorophenol 58-90-2 1xE-02
Tetraethyl lead 78-00-2 4xE-06
Thiourea 62-56-6 2xE-04
Toluene 108-88-3 1xE+01
Toxaphene 8001-35-2 5xE-03
1,1,2-Trichloroethane 79-00-5 6xE-03
Trichloroethylene 79-01-6 5xE-03
Trichloromonofluoromethane 75-69-4 1xE+01
2,4,5-Trichlorophenol 95-95-4 4xE+00
2,4,6-Trichlorophenol 88-06-2 4xE+00
Vanadium pentoxide 1314-62-1 7xE-01
Vinyl chloride 75-01-4 2xE-03
----------------------------------------------------------------------

[FNa1] The health-based concentration limits for Appendix VIII chapter 11 constituents for which a health-based concentration is not provided below is 2xE-06 mg/kg.
[FNa2] The levels specified in this appendix and the default level of 0.002 micrograms per kilogram or the level of detection for constituents as identified in Note 1 of this appendix are administratively stayed under the condition, for those constituents specified in section 66266.112(b)(1), that the owner or operator complies with alternative levels defined as the disposal restriction limits specified in section 66268.43 of chapter 18 of the California Code of Regulations for F039 nonwastewaters. See section 66266.112(b)(2)(A).

Note: Authority cited: Sections 25150, 25159, 25159.5, 25245, 58004 and 58012, Health and Safety Code. Reference: Sections 25159 and 25159.5, Health and Safety Code; and 40 CFR part 266, Appendix VII.





Appendix VIII. -Potential PICs for Determination of Exclusion of Waste-Derived Residues
PICs Found in Stack Effluents
-----------------------------------------------------
Volatiles Semivolatiles
-----------------------------------------------------
Benzene Bis(2-ethylhexyl)phthalate
Toluene Napthalene
Carbon tetrachloride Phenol
Chloroform Diethyl phthalate
Methylene chloride Butyl benzyl phthalate
Trichloroethylene 2,4-Dimethylphenol
Tetrachloroethylene o-Dichlorobenzene
1,1,1-Trichloroethane m-Dichlorobenzene
Chlorobenzene p-Dichlorobenzene
cis-1,4-Dichloro-2-butene Hexachlorobenzene
Bromochloromethane 2,4,6-Trichlorophenol
Bromodichloromethane Fluoranthene
Bromoform o-Nitrophenol
Bromomethane 1,2,4-Trichlorobenzene
Methylene bromide o-Chlorophenol
Methyl ethyl ketone Pentachlorophenol
Pyrene
Dimethyl phthalate
Mononitrobenzene
2,6-Toluene diisocyanate


Note: Authority cited: Sections 25150, 25159, 25159.5, 25245, 58004 and 58012, Health and Safety Code. Reference: Sections 25159 and 25159.5, Health and Safety Code; and 40 CFR part 266, Appendix VIII.





Appendix IX -Methods Manual for Compliance With the BIF Regulations Burning Hazardous Waste in Boilers and Industrial Furnaces
TABLE OF CONTENTS

1.0 Introduction
2.0 Performance Specifications for Continuous Emission Monitoring Systems
2.1 Performance Specifications for Continuous Emission Monitoring of Carbon Monoxide and Oxygen for Incinerators, Boilers, and Industrial Furnaces Burning Hazardous Waste
2.2 Performance Specifications for Continuous Emission Monitoring of Hydrocarbons for Incinerators, Boilers, and Industrial Furnaces
3.0 Sampling and Analytical Methods
4.0 Procedure for Estimating Toxicity Equipment or Chlorinated Dibenzo-P-Dioxin and Dibenzofuran Congeners
5.0 Hazardous Waste Combustion Air Quality Screening Procedure
6.0 Simplified Land Use Classification Procedure for Compliance With Tier I and Tier II Limits
7.0 Statistical Methodology for Bevill Residue Determinations
8.0 Procedures for Determining Default Values for Air Pollution Control System Removal Efficiencies
8.1 APCS RE Default Values for Metals
8.2 APCS RE Default Values for HCl and Cl 2
8.3 APCS RE Default Values for Ash
8.4 References
9.0 Procedures for Determining Default Values for Partitioning of Metals, Ash, and Total Chloride/Chlorine
9.1 Partitioning Default Value for Metals
9.2 Special Procedures for Chlorine, HCl, and Cl
9.3 Special Procedures for Ash
9.4 Use of Engineering Judgement to Estimate Partitioning and APCS RE Values
9.5 Restrictions on Use of Test Data
10.0 Alternate Methodology for Implementing Metals Controls
10.1 Applicability
10.2 Introduction
10.3 Basis
10.4 Overview
10.5 Implementation Procedures
10.6 Precompliance Procedures
Appendix A-Statistics
SECTION 1.0 INTRODUCTION
This document presents required methods for demonstrating compliance with the State of California, Department of Toxic Substances Control regulations governing boilers and industrial furnaces (BIFs) burning hazardous waste (see Title 22, Chapter 16, article 8). Included in this document are:
1. Performance Specifications for Continuous Emission Monitoring (CEM) of Carbon Monoxide, Oxygen, and Hydrocarbons in Stack Gases.
2. Sampling and Analytical (S&A) Methods for Multiple Metals, Hexavalent Chromium, HCl and Chlorine, Polychlorinated Dibenzo-p-dioxins and Dibenzofurans, and Aldehydes and Ketones.
3. Procedures for Estimating the Toxicity Equivalency of Chlorinated Dibenzo-p-dioxin and Dibenzofuran Congeners.
4. Hazardous Waste Combustion Air Quality Screening Procedures (HWCAQSP).
5. Simplified Land Use Classification Procedure for Compliance with Tier I and Tier II Limits.
6. Statistical Methodology for Bevill Residue Determinations.
7. Procedures for Determining Default Values for Air Pollution Control System Removal Efficiencies.
8. Procedures for Determining Default Values for Partitioning of Metals, Ash, and Total Chloride/Chlorine.
9. Alternate Methodology for Implementing Metals Controls.
Additional methods referenced in article 8 of chapter 16 but not included in this document can be found in 40 CFR parts 60 and 61, and "Test Methods for Evaluating Solid Wastes, Physical/Chemical Methods" (SW-846).
The CEM performance specifications of section 2.0, the S&A methods of section 3.0 and the toxicity equivalency procedure for dioxins and furans of section 4.0 are required procedures for determining compliance with BIF regulations. The CEM performance specifications and the S&A methods are interim. The finalized CEM performance specifications and methods will be published in SW-846 or 40 CFR parts 60 and 61.
SECTION 2.0 PERFORMANCE SPECIFICATIONS FOR CONTINUOUS EMISSION MONITORING SYSTEMS
2.1 Performance Specifications for Continuous Emission Monitoring of Carbon Monoxide and Oxygen for Incinerators, Boilers, and Industrial Furnaces Burning Hazardous Waste
2.1.1 Applicability and Principle
2.1.1.1 Applicability. These performance specifications apply to carbon monoxide (CO) and oxygen (O 2) continuous emission monitoring systems (CEMSs) installed on incinerators, boilers, and industrial furnaces burning hazardous waste. The specifications include procedures which are intended to be used to evaluate the acceptability of the CEMS at the time of its installation or whenever specified in regulations or permits. The procedures are not designed to evaluate CEMS performance over an extended period of time. The source owner or operator is responsible for the proper calibration, maintenance, and operation of the CEMS at all times.
2.1.1.2 Principle. Installation and measurement location specifications, performance and equipment specifications, test and data reduction procedures, and brief quality assurance guidelines are included in the specifications. Calibration drift, relative accuracy, calibration error, and response time tests are conducted to determine conformance of the CEMS with the specifications.
2.1.2 Definitions
2.1.2.1 Continuous Emission Monitoring System (CEMS). A continuous monitor is one in which the sample to be analyzed passes the measurement section of the analyzer without interruption, and which evaluates the detector response to the sample at least once each 15 seconds and computes and records the results at least every 60 seconds. A CEMS consists of all the equipment used to acquire data and includes the sample extraction and transport hardware, the analyzer(s), and the data recording/processing hardware and software.
2.1.2.2 Monitoring System Types. The specification require CEMSs capable of accepting calibration gases. Alternative system designs may be used if approved by the Director. There are two basic types of monitoring systems: extractive and in-situ.
2.1.2.2.1 Extractive. Systems that use a pump or other mechanical, pneumatic, or hydraulic means to draw a sample of the stack or flue gas and convey it to a remotely located analyzer.
2.1.2.2.2 In-situ. Systems that perform an analysis without removing a sample from the stack. Point in-situ analyzers place the sensing or detecting element directly in the flue gas stream. Cross-stack in-situ analyzers measure the parameter of interest by placing a source beam on one side of the stack and the detector (in single-pass instruments) or a retroreflector (in double-pass instruments) on the other side, and measuring the parameter of interest (e.g., CO) by the attenuation of the beam by the gas in its path.
2.1.2.3 Instrument Measurement Range. The difference between the minimum and the maximum concentration that can be measured by a specific instrument. The minimum is often stated or assumed to be zero and the range expressed only as the maximum.
2.1.2.4 Span or Span Value. Full scale instrument measurement range.
2.1.2.5 Calibration Drift (CD). The difference in the CEMS output readings from the established reference value after a stated period of operation during which no unscheduled maintenance, repair, or adjustment takes place. A CD test is performed to demonstrate the stability of the CEMS calibration over time.
2.1.2.6 Response Time. The time interval between the start of a step change in the system input (e.g., change of calibration gas) and the time when the data recorder displays 95 percent of the final value.
2.1.2.7 Accuracy. A measure of agreement between a measured value and an accepted or true value, expressed as the percentage difference between the true and measured values relative to the true value. For these performance specifications, accuracy is checked by conducting a calibration error (CE) test and a relative accuracy (RA) test. Certain facilities, such as those using solid waste or batch-fed processes, may observe long periods of almost no CO emissions with brief, high-level CO emission spikes. These facilities, as well as facilities whose CO emissions never exceed 5-10 ppm, may need to be exempted from the RA requirement because the RA test procedure cannot ensure acquisition of meaningful test results under these conditions. An alternative procedure for accuracy determination is described in section 2.1.9.
2.1.2.8 Calibration Error (CE). The difference between the concentration indicated by the CEMS and the known concentration of the cylinder gas. A CE test procedure is performed to document the accuracy and linearity of the monitoring equipment over the entire measurement range.
2.1.2.9 Relative Accuracy (RA). A comparison of the CEMS response to a value measured by a performance test method (PTM). The PA test is used to validate the calibration technique and verify the ability of the CEMS to provide representative and accurate measurements.
2.1.2.10 Performance Test Method (PTM). The sampling and analysis procedure used to obtain reference measurements for comparison to CEMS measurements. The applicable test methods are Method 10, 10A, or 10B (for the determination of CO) and Method 3 or 3A (for the determination of O 2). These methods are found in 40 CFR part 60, appendix A.
2.1.2.11 Performance Specification Test (PST) Period. The period during which CD, CE, response time, and RA tests are conducted.
2.1.2.12 Centroidal Area. A concentric area that is geometrically similar to the stack or duct cross section and is no greater than 1 percent of the stack or duct cross-sectional area.
2.1.3 Installation and Measurement Location Specifications
2.1.3.1 CEMS Installation and Measurement Locations. The CEMS shall be installed in a location in which measurements representative of the source's emissions can be obtained. The optimum location of the sample interface for the CEMS is determined by a number of factors, including ease of access for calibration and maintenance, the degree to
which sample conditioning will be required, the degree to which it represents total emissions, and the degree to which it represents the combustion situation in the firebox. The location should be as free from in-leakage influences as possible and reasonably free from severe flow disturbances. The sample location should be at least two equivalent duct diameters downstream from the nearest control device, point of pollutant generation, or other point at which a change in the pollutant concentration or emission rate occurs and at least 0.5 diameter upstream from the exhaust or control device. The equivalent duct diameter is calculated as per 40 CFR part 60, appendix A, method 1, section 2.1. If these criteria are not achievable or if the location is otherwise less than optimum, the possibility of stratification should be checked as described in Section 2.1.3.3 to determine whether the location would cause failure of the relative accuracy test.
2.1.3.1.1 For extractive or point in-situ CEMSs, the measurement point should be within or centrally located over the centroidal area of the stack or duct cross section.
2.1.3.1.2 For cross-stack CEMSs, the effective measurement path should (1) have at least 70 percent of the path within the inner 50 percent of the stack or duct cross-sectional area or (2) be centrally located over any part of the centroidal area.
2.1.3.1.3 Both the CO and O 2 monitors should be installed at the same general location. If this is not possible, they may be installed at different locations if the effluent gases at both sample locations are not stratified and there is no in-leakage of air between sampling locations.
2.1.3.2 Performance Test Method (PTM) Measurement Location and Traverse Points.
2.1.3.2.1 Select an accessible PTM measurement point at least two equivalent diameters downstream from the nearest control device, the point of CO generation, or other point at which a change in the CO concentration may occur, and at least a half equivalent diameter upstream from the effluent exhaust or control device. When pollutant concentration changes are due solely to diluent leakage (e.g., air heater leakages) and CO and O 2 are simultaneously measured at the same location, one half diameter may be used in place of two equivalent diameters. The CEMS and PTM locations need not be the same.
2.1.3.2.2 Select traverse points that ensure acquisition of representative samples over the stack or duct cross section. At a minimum, establish a measurement line that passes through the centroidal area in the direction of any expected stratification. If this line interferes with the CEMS measurements, displace the line up to 30 cm (or 5 percent of the equivalent diameter of the cross section, whichever is less) from the centroidal area. Locate three traverse points at 17, 50, and 83 percent of the measurement line. If the measurement line is no longer than 2.4 meters and pollutant stratification is not expected, the tester may choose to locate the three traverse points on the line at 0.4, 1.2, and 2.0 meters from the stack or duct wall. This option must not be used at a site located within eight equivalent diameters downstream of a flow disturbance. The tester may select other traverse points, provided that they can be shown to the satisfaction of the Director to provide a representative sample over the stack or duct cross-section. Conduct all necessary PTM tests within 3 cm of the selected traverse points. Sampling must not be performed within 3 cm of the duct or stack inner wall.
2.1.3.3 Stratification Test Procedure. Stratification is defined as a difference in excess of 10 percent between the average concentration in the duct or stack and the concentration at any point more than 1.0 meter from the duct or stack wall. To determine whether effluent stratification exists, a dual probe system should be used to determine the average effluent concentration while measurements at each traverse point are being made. One probe, located at the stack or duct centroid, is used as a stationary reference point to indicate the change in effluent concentration over time. The second probe is used for sampling the traverse points specified in method 1, appendix A, 40 CFR part 60. The monitoring system samples sequentially at the reference and traverse points throughout the testing period for five minutes at each point.
2.1.4 CEMS Performance and Equipment Specifications
Table 2.1-1 summarizes the performance specifications for the CEMSs. Two sets of standards for CO are given; one for low-range and another for high-range measurements. The high-range specifications relate to measurement and quantification of short duration high concentration peaks, while the low-range specifications relate to the overall average operating condition of the burning device. The dual-range specifications can be met by using (1) one analyzer for each range, (2) a dual range unit, or (3) a single measurement range instrument capable of meeting both specifications with a single unit. Adjustments cannot be made to the analyzer between determinations of low- and high-level accuracy within the single measurement range. In the second case, when the concentration exceeds the span of the lower range, the data acquisition system recorder shall switch to the high range automatically.
2.1.4.1 CEMS Span Value. In order to measure high and low concentrations with the same or similar degree of accuracy, the maximum ranges (span values) are specified for low and high range analyzers. The span values are listed in Table 2.1-2. Tier I and Tier II format definitions are established in Title 22, Chapter 16, Article 8.
Table 2.1-1 -Performance Specifications of CO and O 2 Monitors

________________________________________________________________________
CO monitors
Parameter Low range High range O2
________________________________________________________________________
Calibration drift 24 hours. <6 ppm [FN1] <90 ppm <0.5% O 2
Calibration error. <10 ppm [FN1] <150 ppm <0.5% O 2
Response time. <2 min <2 min <2 min
Relative accuracy [FN2]. ( [FN3]) ( [FN3]) (incorporated in
CO RA
calculation)
________________________________________________________________________

[FNFOOTNOTE:] 1 For Tier II, CD and CE are <3% and <5% of twice the permit limit, respectively.
[FNFOOTNOTE:] 2 Expressed as the sum of the mean absolute value plus the 95% confidence interval of a series of measurements.
[FNFOOTNOTE:] 3 The greater of 10% of PTM or 10 ppm.
Table 2.1-2 -CEMS Span Values for CO and O 2 Monitors

_______________________________________________________________
CO monitors
Low range (ppm) High range (ppm) O 2
(percent)
_______________________________________________________________
Tier I rolling 200 3,000 25
average format.
Tier II rolling 2 X permit limit. 3,000 25
average format.
_______________________________________________________________

2.1.4.2 Daily Calibration Gas Values. The owner or operator must choose calibration gas concentrations (or calibration filters for in-situ systems) that include zero and high-level calibration values for the daily calibration checks. For a single measurement range monitor, three CO calibration gas concentrations (or calibration filters for in-situ systems) shall be used, i.e., the zero and high-level concentrations of the low-range CO analyzer and the high-level concentration of the high-range CO analyzer.
2.1.4.2.1 The zero level for the CO or O 2 analyzer may be between zero and 20 percent of the span value, e.g., 0-40 ppm for low-range CO analyzer, 0-600 ppm for the high-range CO analyzer, and 0-5 percent for the O 2 analyzer (for Tier I).
2.1.4.2.2 The high-level concentration for the CO or O 2 analyzer shall be between 50 and 90 percent of the span value, i.e., 100-180 ppm for the low-range CO analyzer, 1500-2700 ppm for the high-range CO analyzer, and 12.5-22.5 percent O 2 for the O 2 analyzer.
2.1.4.3 Data Recorder Scale. The strip chart recorder, computer, or digital recorder must be capable of recording all readings within the CEMS's measurement range and shall have a resolution of 0.5 percent of span value, i.e., 1 ppm CO for low-range CO analyzer, 15 ppm CO for high-range CO analyzer, and 0.1 percent O 2 for the O 2 analyzer.
2.1.4.4 Response Time. The response time for the CO or O 2 monitor shall not exceed 2 minutes to achieve 95 percent of the final stable value.
2.1.4.5 Calibration Drift. The CEMS must allow the determination of CD at the zero and high-level values. The CD must be determined separately for CO and O 2 monitors in terms of concentration. The CO CEMS calibration response must not drift or deviate from the reference value of the calibration gas (or calibration filters for in-situ systems) by more than 3 percent of the span value after each 24-hour period of the 7-day test, i.e., 6 ppm CO for the low-range analyzer (Tier I) and 90 ppm for the high-range analyzer, at both zero and high levels. The O 2 monitor calibration response must not drift or deviate from the reference value by more than 0.5 percent O 2 at both zero and high levels. (continued)