CCLME.ORG - 40 CFR PART 58—AMBIENT AIR QUALITY SURVEILLANCE
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4.5 Transition Period. A variable period of time is proposed for phasing in the operation of all required PAMS. Within 1 year after (1) February 12, 1993, (2) or date of redesignation or reclassification of any existing O3 nonattainment area to serious, severe, or extreme, or (3) the designation of a new area and classification to serious, severe, or extreme O3 nonattainment, a minimum of one type (2) site must be operating. Operation of the remaining sites must, at a minimum, be phased in at the rate of one site per year during subsequent years as outlined in the approved PAMS network description provided by the State.

4.6 Meteorological Monitoring. In order to support monitoring objectives associated with the need for various air quality analyses, model inputs and performance evaluations, meteorological monitoring including wind measurements at 10 meters above ground is required at each PAMS site. Monitoring should begin with site establishment. In addition, upper air meteorological monitoring is required for each PAMS area. Upper air monitoring should be initiated as soon as possible, but no later than 2 years after (1) February 12, 1993, (2) or date of redesignation or reclassification of any existing O3 nonattainment area to serious, severe, or extreme, or (3) the designation of a new area and classification to serious, severe, or extreme O3 nonattainment. The upper air monitoring site may be located separately from the type (1) through (4) sites, but the location should be representative of the upper air data in the nonattainment area. Upper air meteorological data must be collected during those days specified for monitoring by the sampling frequencies in table 2. of section 4.4 of this appendix D in accordance with current EPA guidance.

5. Summary.

Table 6 of this appendix shows by pollutant, all of the spatial scales that are applicable for SLAMS and the required spatial scales for NAMS. There may also be some situations, as discussed later in appendix E of this part, where additional scales may be allowed for NAMS purposes.


Table 6_Summary of Spatial Scales for SLAMS and Required Scales for NAMS
----------------------------------------------------------------------------------------------------------------
Scales Applicable for SLAMS
Spatial Scale -----------------------------------------------------------------------------------
SO2 CO O3 NO2 Pb PM10 PM2.5
----------------------------------------------------------------------------------------------------------------
Micro....................... .......... [bcheck] .......... .......... [bcheck] [bcheck] [bcheck]
Middle...................... [bcheck] [bcheck] [bcheck] [bcheck] [bcheck] [bcheck] [bcheck]
Neighborhood................ [bcheck] [bcheck] [bcheck] [bcheck] [bcheck] [bcheck] [bcheck]
Urban....................... [bcheck] .......... [bcheck] [bcheck] [bcheck] [bcheck] [bcheck]
Regional.................... [bcheck] .......... [bcheck] .......... [bcheck] [bcheck] [bcheck]
Scales
Required
for NAMS
Micro....................... .......... [bcheck] .......... .......... [bcheck] [bcheck] [bcheck]1
Middle...................... .......... .......... .......... .......... [bcheck] [bcheck] [bcheck]1
Neighborhood................ [bcheck] [bcheck] [bcheck] [bcheck] [bcheck] [bcheck] [bcheck]
Urban....................... .......... .......... [bcheck] [bcheck] .......... .......... [bcheck]2
Regional.................... .......... .......... .......... .......... .......... .......... [bcheck]2
----------------------------------------------------------------------------------------------------------------
\1\ Only permitted if representative of many such micro-scale environments in a residential district (for middle
scale, at least two).
\2\ Either urban or regional scale for regional transport sites.


6. References

1. Ludwig, F. L., J. H. S. Kealoha, and E. Shelar. Selecting Sites for Monitoring Total Suspended Particulates. Stanford Research Institute, Menlo Park, CA. Prepared for U.S. Environmental Protection Agency, Research Triangle Park, NC. EPA Publication No. EPA–450/3–77–018. June 1977, revised December 1977.

2. Ball, R. J. and G. E. Anderson. Optimum Site Exposure Criteria for SO2 Monitoring. The Center for the Environment and Man, Inc., Hartford, CT. Prepared for U.S. Environmental Protection Agency, Research Triangle Park, NC. EPA Publication No. EPA–450/3–77–013. April 1977.

3. Ludwig, F. L. and J. H. S. Kealoha. Selecting Sites for Carbon Monoxide Monitoring. Stanford Research Institute, Menlo Park, CA. Prepared for U.S. Environmental Protection Agency, Research Triangle Park, NC. EPA Publication No. EPA–450/3–75–077. September 1975.

4. Ludwig, F. L. and E. Shelar. Site Selecting for the Monitoring of Photochemical Air Pollutants. Stanford Research Institute, Menlo Park, CA. Prepared for U.S. Environmental Protection Agency, Research Triangle Park, NC. EPA Publication No. EPA–450/3–78–013. April 1978.

5. Guideline on Air Quality Models. OAQPS, U.S. Environmental Protection Agency, Research Triangle Park, NC. OAQPS No. 1.2–080. April 1978.

6. Lead Guideline Document, U. S. Environmental Protection Agency, Research Triangle Park, NC. EPA–452/R–93–009.

7. Air Quality Criteria for Lead. Office of Research and Development, U.S. Environmental Protection Agency, Washington, DC. EPA–600/8–83–028 aF-dF, 1986, and supplements EPA–600/8–89/049F, August 1990. (NTIS document numbers PB87–142378 and PB91–138420.)

8. Johnson, D. E., et al. Epidemiologic Study of the Effects of Automobile Traffic on Blood Lead Levels, Southwest Research Institute, Houston, TX. Prepared for U.S. Environmental Protection Agency, Research Triangle Park, NC. EPA–600/1–78–055. August 1978.

9. Optimum Site Exposure Criteria for Lead Monitoring. PEDCo Environmental, Inc., Cincinnati, OH. Prepared for U.S. Environmental Protection Agency, Research Triangle Park, NC. EPA Contract No. 68–02–3013. (May 1981.)

10. “Guidance for Conducting Ambient Air Monitoring for Lead Around Point Sources,” Office of Air Quality Planning and Standards, U.S. Environmental Protection Agency, Research Triangle Park, NC EPA–454/R–92–009, May 1997.

11. Cooper, J.A., et. al. Summary of the Portland Aerosol Characterization Study. (Presented at the 1979 Annual Air Pollution Association Meeting, Cincinnati, OH. APCA #79–24.4).

12. Bradway, R.M. and F.A. Record. National Assessment of the Urban Particulate Problem. Volume 1. Prepared for U.S. Environmental Protection Agency, Research Triangle Park, NC. EPA–450/3–76–024. July 1976.

13. U.S. Environmental Protection Agency, Air Quality Criteria for Particulate Matter and Sulfur Oxides, Volume 2. Environmental Criteria and Assessment Office, Research Triangle Park, NC. December 1981.

14. Watson, J.G., et al. Analysis of Inhalable and Fine Particulate Matter Measurements. Prepared for U.S. Environmental Protection Agency, Research Triangle Park, NC. EPA–450/4–81–035. December 1981.

15. Record, F.A. and L.A. Baci. Evaluation on Contribution of Wind Blown Dust from the Desert Levels of Particulate Matter in Desert Communities. GCA Technology Division, Bedford, MA. Prepared for U.S. Environmental Protection Agency, Research Triangle Park, NC. EPA–450/2–80–078. August 1980.

16. Goldstein, E.A. and Paly M. The Diesel Problem in New York City. Project on the Urban Environment. Natural Resources Defense Council, Inc., New York, NY. April 1985.

17. Koch, R.C. and H.E. Rector. Optimum Network Design and Site Exposure Criteria for Particulate Matter. GEOMET Technologies, Inc., Rockville, MD. Prepared for U.S. Environmental Protection Agency, Research Triangle Park, NC. EPA Contract No. 68–02–3584. EPA 450/4–87–009. May 1987.

18. Watson et al. Guidance for Network Design and Optimum Site Exposure for PM2.5 and PM10. Prepared for U.S. Environmental Protection Agency, Research Triangle Park, NC.

19. National Air Pollutant Emissions Trends, 1900–1995, Office of Air Quality Planning and Standards, U. S. Environmental Protection Agency, Research Triangle Park, NC. EPA–454/R96–007, October 1996, updated annually.

[44 FR 27571, May 10, 1979]

Editorial Note: For Federal Register citations affecting appendix D to part 58, see the List of CFR Sections Affected, which appears in the Finding Aids section of the printed volume and on GPO Access.

Effective Date Note: At 60 FR 52323, October 6, 1995, appendix D to part 58 was amended in part by adding Section 2.2. This section contains information collection and recordkeeping requirements and will not become effective until approval has been given by the Office of Management and Budget.

Appendix E to Part 58—Probe and Monitoring Path Siting Criteria for Ambient Air Quality Monitoring
top
1. Introduction

2 Sulfur Dioxide (SO2), Ozone (O3), and Nitrogen Dioxide (NO2)

2.1 Horizontal and Vertical Placement

2.2 Spacing from Minor Sources (Applicable to SO2 and O3 Monitoring Only)

2.3 Spacing From Obstructions

2.4 Spacing From Trees

2.5 Spacing From Roadways (Applicable to O3 and NO2 Only)

2.6 Cumulative Interferences on a Monitoring Path

2.7 Maximum Monitoring Path Length

3 [Reserved]

4. Carbon Monoxide (CO)

4.1 Horizontal and Vertical Placement

4.2 Spacing From Obstructions

4.3 Spacing From Roadways

4.4 Spacing From Trees and Other Considerations

4.5 Cumulative Interferences on a Monitoring Path

4.6 Maximum Monitoring Path Length

5–6 [Reserved]

7. Lead(Pb)

7.1 Vertical Placement

7.2 Spacing From Obstructions

7.3 Spacing From Roadways

7.4 Spacing From Trees and Other Considerations.

8. Particulate Matter (PM10 and PM2.5)

8.1 Vertical Placement

8.2 Spacing From Obstructions

8.3 Spacing From Roadways

8.4 Other Considerations

9. Probe Material and Pollutant Sample Residence Time

10. Photochemical Assessment Monitoring Stations (PAMS)

10.1 Horizontal and Vertical Placement

10.2 Spacing From Obstructions

10.3 Spacing From Roadways

10.4 Spacing From Trees

11. Discussion and Summary

12. Summary

13. References

1. Introduction

This appendix contains specific location criteria applicable to ambient air quality monitoring probes and monitoring paths after the general station siting has been selected based on the monitoring objectives and spatial scale of representation discussed in appendix D of this part. Adherence to these siting criteria is necessary to ensure the uniform collection of compatible and comparable air quality data.

The probe and monitoring path siting criteria discussed below must be followed to the maximum extent possible. It is recognized that there may be situations where some deviation from the siting criteria may be necessary. In any such case, the reasons must be thoroughly documented in a written request for a waiver that describes how and why the proposed siting deviates from the criteria. This documentation should help to avoid later questions about the validity of the resulting monitoring data. Conditions under which the EPA would consider an application for waiver from these siting criteria are discussed in section 11 of this appendix.

The spatial scales of representation used in this appendix, i.e., micro, middle, neighborhood, urban, and regional, are defined and discussed in appendix D of this part. The pollutant-specific probe and monitoring path siting criteria generally apply to all spatial scales except where noted otherwise. Specific siting criteria that are phrased with a “must” are defined as requirements and exceptions must be approved through the waiver provisions. However, siting criteria that are phrased with a “should” are defined as goals to meet for consistency but are not requirements.

2. Sulfur Dioxide (SO2), Ozone (O3), and Nitrogen Dioxide (NO2)

Open path analyzers may be used to measure SO2, O3, and NO2 at SLAMS/NAMS sites for middle, neighborhood, urban, and regional scale measurement applications. Additional information on SO2, NO2, and O3 monitor siting criteria may be found in references 11 and 13.

2.1 Horizontal and Vertical Placement. The probe or at least 80 percent of the monitoring path must be located between 3 and 15 meters above ground level. The probe or at least 90 percent of the monitoring path must be at least 1 meter vertically or horizontally away from any supporting structure, walls, parapets, penthouses, etc., and away from dusty or dirty areas. If the probe or a significant portion of the monitoring path is located near the side of a building, then it should be located on the windward side of the building relative to the prevailing wind direction during the season of highest concentration potential for the pollutant being measured.

2.2 Spacing from Minor Sources (Applicable to SO2 and O3 Monitoring Only). Local minor sources of SO2 can cause inappropriately high concentrations of SO2 in the vicinity of probes and monitoring paths for SO2. Similarly, local sources of nitric oxide (NO) and ozone-reactive hydrocarbons can have a scavenging effect causing unrepresentatively low concentrations of O3 in the vicinity of probes and monitoring paths for O3. To minimize these potential interferences, the probe or at least 90 percent of the monitoring path must be away from furnace or incineration flues or other minor sources of SO2 or NO, particularly for open path analyzers because of their potential for greater exposure over the area covered by the monitoring path. The separation distance should take into account the heights of the flues, type of waste or fuel burned, and the sulfur content of the fuel. It is acceptable, however, to monitor for SO2 near a point source of SO2 when the objective is to assess the effect of this source on the represented population.

2.3 Spacing From Obstructions. Buildings and other obstacles may possibly scavenge SO2, O3, or NO2. To avoid this interference, the probe or at least 90 percent of the monitoring path must have unrestricted airflow and be located away from obstacles so that the distance from the probe or monitoring path is at least twice the height that the obstacle protrudes above the probe or monitoring path. Generally, a probe or monitoring path located near or along a vertical wall is undesirable because air moving along the wall may be subject to possible removal mechanisms. A probe must have unrestricted airflow in an arc of at least 270 degrees around the inlet probe, or 180 degrees if the probe is on the side of a building. This arc must include the predominant wind direction for the season of greatest pollutant concentration potential. A sampling station having a probe located closer to an obstacle than this criterion allows should be classified as middle scale rather than neighborhood or urban scale, since the measurements from such a station would more closely represent the middle scale. A monitoring path must be clear of all trees, brush, buildings, plumes, dust, or other optical obstructions, including potential obstructions that may move due to wind, human activity, growth of vegetation, etc. Temporary optical obstructions, such as rain, particles, fog, or snow, should be considered when siting an open path analyzer. Any of these temporary obstructions that are of sufficient density to obscure the light beam will affect the ability of the open path analyzer to continuously measure pollutant concentrations.

Special consideration must be devoted to the use of open path analyzers due to their inherent potential sensitivity to certain types of interferences, or optical obstructions. While some of these potential interferences are comparable to those to which point monitors are subject, there are additional sources of potential interferences which are altogether different in character. Transient, but significant obscuration of especially longer measurement paths could be expected to occur as a result of certain prevailing meteorological conditions (e.g., heavy fog, rain, snow) and/or aerosol levels that are of a sufficient density to prevent the open path analyzer's light transmission. If certain compensating measures are not otherwise implemented at the onset of monitoring (e.g., shorter path lengths, higher light source intensity), data recovery during periods of greatest primary pollutant potential could be compromised. For instance, if heavy fog or high particulate levels are coincident with periods of projected NAAQS-threatening pollutant potential, the representativeness of the resulting data record in reflecting maximum pollutant concentrations may be substantially impaired despite the fact that the site may otherwise exhibit an acceptable, even exceedingly high overall valid data capture rate.

In seeking EPA approval for inclusion of a site using an open path analyzer into the formal SLAMS/NAMS or PSD network, monitoring agencies must submit an analysis which evaluates both obscuration potential for a proposed path length for the subject area and the effect this potential is projected to have on the representativeness of the data record. This analysis should include one or more of the following elements, as appropriate for the specific circumstance: climatological information, historical pollutant and aerosol information, modeling analysis results, and any related special study results.

2.4 Spacing From Trees. Trees can provide surfaces for SO2, O3, or NO2 adsorption or reactions and obstruct wind flow. To reduce this possible interference, the probe or at least 90 percent of the monitoring path should be 20 meters or more from the drip line of trees. If a tree or trees could be considered an obstacle, the probe or 90 percent of the monitoring path must meet the distance requirements of section 2.3 and be at least 10 meters from the drip line of the tree or trees. Since the scavenging effect of trees is greater for O3 than for other criteria pollutants, strong consideration of this effect must be given to locating an O3 probe or monitoring path to avoid this problem.

2.5 Spacing From Roadways (Applicable to O3 and NO2 Only). In siting an O3 analyzer, it is important to minimize destructive interferences from sources of NO, since NO readily reacts with O3. In siting NO2 analyzers for neighborhood and urban scale monitoring, it is important to minimize interferences from automotive sources. Table 1 provides the required minimum separation distances between a roadway and a probe and between a roadway and at least 90 percent of a monitoring path for various ranges of daily roadway traffic. A sampling station having a point analyzer probe located closer to a roadway than allowed by the table 1 requirements should be classified as middle scale rather than neighborhood or urban scale, since the measurements from such a station would more closely represent the middle scale. If an open path analyzer is used at a site, the monitoring path(s) must not cross over a roadway with an average daily traffic count of 10,000 vehicles per day or more. For those situations where a monitoring path crosses a roadway with fewer than 10,000 vehicles per day, one must consider the entire segment of the monitoring path in the area of potential atmospheric interference from automobile emissions. Therefore, this calculation must include the length of the monitoring path over the roadway plus any segments of the monitoring path that lie in the area between the roadway and the minimum separation distance, as determined from table 1. The sum of these distances must not be greater than 10 percent of the total monitoring path length.


Table 1_Minimum Separation Distance Between Roadways and Probes or
Monitoring Paths for Monitoring Neighborhood_and Urban_Scale Ozone and
Nitrogen Dioxide
------------------------------------------------------------------------
Minimum
separation
Roadway average daily traffic, vehicles per day distance,\1\
meters
------------------------------------------------------------------------
[le]10,000................................................ 10
15,000.................................................... 20
20,000.................................................... 30
40,000.................................................... 50
70,000.................................................... 100
>=110,000................................................. 250
------------------------------------------------------------------------
\1\ Distance from the edge of the nearest traffic lane. The distance for
intermediate traffic counts should be interpolated from the table
values based on the actual traffic count.


2.6 Cumulative Interferences on a Monitoring Path. The cumulative length or portion of a monitoring path that is affected by minor sources, obstructions, trees, or roadways must not exceed 10 percent of the total monitoring path length.

2.7 Maximum Monitoring Path Length. The monitoring path length must not exceed 1 kilometer for analyzers in neighborhood, urban, or regional scale. For middle scale monitoring sites, the monitoring path length must not exceed 300 meters. In areas subject to frequent periods of dust, fog, rain, or snow, consideration should be given to a shortened monitoring path length to minimize loss of monitoring data due to these temporary optical obstructions. For certain ambient air monitoring scenarios using open path analyzers, shorter path lengths may be needed in order to ensure that the monitoring station meets the objectives and spatial scales defined for SLAMS in appendix D. Therefore, the Regional Administrator or the Regional Administrator's designee may require shorter path lengths, as needed on an individual basis, to ensure that the SLAMS meet the appendix D requirements. Likewise, the Administrator or the Administrator's designee may specify the maximum path length used at monitoring stations designated as NAMS or PAMS as needed on an individual basis.

3. [Reserved]

4. Carbon Monoxide (CO)

Open path analyzers may be used to measure CO at SLAMS/NAMS sites for middle or neighborhood scale measurement applications. Additional information on CO monitor siting criteria may be found in reference 12.

4.1 Horizontal and Vertical Placement. Because of the importance of measuring population exposure to CO concentrations, air should be sampled at average breathing heights. However, practical factors require that the inlet probe be higher. The required height of the inlet probe for CO monitoring is therefore 3± 1/2 meters for a microscale site, which is a compromise between representative breathing height and prevention of vandalism. The recommended 1 meter range of heights is also a compromise to some extent. For consistency and comparability, it would be desirable to have all inlets at exactly the same height, but practical considerations often prevent this. Some reasonable range must be specified and 1 meter provides adequate leeway to meet most requirements.

For the middle and neighborhood scale stations, the vertical concentration gradients are not as great as for the microscale station. This is because the diffusion from roads is greater and the concentrations would represent larger areas than for the microscale. Therefore, the probe or at least 80 percent of the monitoring path must be located between 3 and 15 meters above ground level for middle and neighborhood scale stations. The probe or at least 90 percent of the monitoring path must be at least 1 meter vertically or horizontally away from any supporting structure, walls, parapets, penthouses, etc., and away from dusty or dirty areas. If the probe or a significant portion of the monitoring path is located near the side of a building, then it should be located on the windward side of the building relative to both the prevailing wind direction during the season of highest concentration potential and the location of sources of interest, i.e., roadways.

4.2 Spacing From Obstructions. Buildings and other obstacles may restrict airflow around a probe or monitoring path. To avoid this interference, the probe or at least 90 percent of the monitoring path must have unrestricted airflow and be located away from obstacles so that the distance from the probe or monitoring path is at least twice the height that the obstacle protrudes above the probe or monitoring path. A probe or monitoring path located near or along a vertical wall is undesirable because air moving along the wall may be subject to possible removal mechanisms. A probe must have unrestricted airflow in an arc of at least 270 degrees around the inlet probe, or 180 degrees if the probe is on the side of a building. This arc must include the predominant wind direction for the season of greatest pollutant concentration potential. A monitoring path must be clear of all trees, brush, buildings, plumes, dust, or other optical obstructions, including potential obstructions that may move due to wind, human activity, growth of vegetation, etc. Temporary optical obstructions, such as rain, particles, fog, or snow, should be considered when siting an open path analyzer. Any of these temporary obstructions that are of sufficient density to obscure the light beam will affect the ability of the open path analyzer to continuously measure pollutant concentrations.

Special consideration must be devoted to the use of open path analyzers due to their inherent potential sensitivity to certain types of interferences, or optical obstructions. While some of these potential interferences are comparable to those to which point monitors are subject, there are additional sources of potential interferences which are altogether different in character. Transient, but significant obscuration of especially longer measurement paths could be expected to occur as a result of certain prevailing meteorological conditions (e.g., heavy fog, rain, snow) and/or aerosol levels that are of a sufficient density to prevent the open path analyzer's light transmission. If certain compensating measures are not otherwise implemented at the onset of monitoring (e.g., shorter path lengths, higher light source intensity), data recovery during periods of greatest primary pollutant potential could be compromised. For instance, if heavy fog or high particulate levels are coincident with periods of projected NAAQS-threatening pollutant potential, the representativeness of the resulting data record in reflecting maximum pollutant concentrations may be substantially impaired despite the fact that the site may otherwise exhibit an acceptable, even exceedingly high overall valid data capture rate.

In seeking EPA approval for inclusion of a site using an open path analyzer into the formal SLAMS/NAMS or PSD network, monitoring agencies must submit an analysis which evaluates both obscuration potential for a proposed path length for the subject area and the effect this potential is projected to have on the representativeness of the data record. This analysis should include one or more of the following elements, as appropriate for the specific circumstance: climatological information, historical pollutant and aerosol information, modeling analysis results, and any related special study results.

4.3 Spacing From Roadways. Street canyon and traffic corridor stations (microscale) are intended to provide a measurement of the influence of the immediate source on the pollution exposure of the population. In order to provide some reasonable consistency and comparability in the air quality data from microscale stations, a minimum distance of 2 meters and a maximum distance of 10 meters from the edge of the nearest traffic lane must be maintained for these CO monitoring inlet probes. This should give consistency to the data, yet still allow flexibility of finding suitable locations.

Street canyon/corridor (microscale) inlet probes must be located at least 10 meters from an intersection and preferably at a midblock location. Midblock locations are preferable to intersection locations because intersections represent a much smaller portion of downtown space than do the streets between them. Pedestrian exposure is probably also greater in street canyon/corridors than at intersections. Also, the practical difficulty of positioning sampling inlets is less at midblock locations than at the intersection. However, the final siting of the monitor must meet the objectives and intent of appendix D, sections 2.4, 3, 3.3, and appendix E, section 4.

In determining the minimum separation between a neighborhood scale monitoring station and a specific line source, the presumption is made that measurements should not be substantially influenced by any one roadway. Computations were made to determine the separation distance, and table 2 provides the required minimum separation distance between roadways and a probe or 90 percent of a monitoring path. Probes or monitoring paths that are located closer to roads than this criterion allows should not be classified as a neighborhood scale, since the measurements from such a station would closely represent the middle scale. Therefore, stations not meeting this criterion should be classified as middle scale.


Table 2_Minimum Separation Distance Between Roadways and Probes or
Monitoring Paths for Monitoring Neighborhood Scale Carbon Monoxide
------------------------------------------------------------------------
Minimum
separation
distance
\1\ for
Roadway average daily traffic, vehicles per day probes or
90% of a
monitoring
path
(meters)
------------------------------------------------------------------------
[le]10,000................................................. 10
15,000.................................................... 25
20,000.................................................... 45
30,000.................................................... 80
40,000.................................................... 115
50,000.................................................... 135
[le]60,000................................................ 150
------------------------------------------------------------------------
\1\ Distance from the edge of the nearest traffic lane. The distance for
intermediate traffic counts should be interpolated from the table
values based on the actual traffic count.


4.4 Spacing From Trees and Other Considerations. Since CO is relatively nonreactive, the major factor concerning trees is as obstructions to normal wind flow patterns. For middle and neighborhood scale stations, trees should not be located between the major sources of CO, usually vehicles on a heavily traveled road, and the monitor. The probe or at least 90 percent of the monitoring path must be 10 meters or more from the drip line of trees which are between the probe or the monitoring path and the road and which extend at least 5 meters above the probe or monitoring path. For microscale stations, no trees or shrubs should be located between the probe and the roadway.

4.5 Cumulative Interferences on a Monitoring Path. The cumulative length or portion of a monitoring path that is affected by obstructions, trees, or roadways must not exceed 10 percent of the total monitoring path length.

4.6 Maximum Monitoring Path Length. The monitoring path length must not exceed 1 kilometer for analyzers used for neighborhood scale monitoring applications, or 300 meters for middle scale monitoring applications. In areas subject to frequent periods of dust, fog, rain, or snow, consideration should be given to a shortened monitoring path length to minimize loss of monitoring data due to these temporary optical obstructions. For certain ambient air monitoring scenarios using open path analyzers, shorter path lengths may be needed in order to ensure that the monitoring station meets the objectives and spatial scales defined for SLAMS in appendix D. Therefore, the Regional Administrator or the Regional Administrator's designee may require shorter path lengths, as needed on an individual basis, to ensure that the SLAMS meet the appendix D requirements. Likewise, the Administrator or the Administrator's designee may specify the maximum path length used at monitoring stations designated as NAMS or PAMS as needed on an individual basis.

5.–6. [Reserved]

7. Lead (Pb)

7.1 Vertical Placement. Optimal placement of the sampler inlet for Pb monitoring should be at breathing height level. However, practical factors such as prevention of vandalism, security, and safety precautions must also be considered when siting a Pb monitor. Given these considerations, the sampler inlet for microscale Pb monitors must be 2–7 meters above ground level. The lower limit was based on a compromise between ease of servicing the sampler and the desire to avoid unrepresentative conditions due to re-entrainment from dusty surfaces. The upper limit represents a compromise between the desire to have measurements which are most representative of population exposures and a consideration of the practical factors noted above.

For middle or larger spatial scales, increased diffusion results in vertical concentration gradients which are not as great as for the small scales. Thus, the required height of the air intake for middle or larger scales is 2–15 meters.

7.2 Spacing From Obstructions. The sampler must be located away from obstacles such as buildings, so that the distance between obstacles and the sampler is at least twice the height that the obstacle protrudes above the sampler.

A minimum of 2 meters of separation from walls, parapets, and penthouses is required for rooftop samplers. No furnace or incinerator flues should be nearby. The height and type of flues and the type, quality, and quantity of waste or fuel burned determine the separation distances. For example, if the emissions from the chimney have high lead content and there is a high probability that the plume would impact on the sampler during most of the sampling period, then other buildings/locations in the area that are free from the described sources should be chosen for the monitoring site.

There must be unrestricted airflow in an arc of at least 270° around the sampler.

Since the intent of the category (a) site is to measure the maximum concentrations from a road or point source, there must be no significant obstruction between a road or point source and the monitor, even though other spacing from obstruction criteria are met. The predominant direction for the season with the greatest pollutant concentration potential must be included in the 270° arc.

7.3. Spacing from Roadways. This criteria applies only to those Pb sites designed to assess lead concentrations from mobile sources. Numerous studies have shown that ambient Pb levels near mobile sources are a function of the traffic volume and are most pronounced at ADT >30,000 within the first 15 meters on the downwind side of the roadways. Numberous studies have shown that ambient lead levels near mobile source are a function of the traffic volume and are most pronounced at ADT =30,000 within the first 15 meters, on the downwind side of the roadways. (1, 16–19) Therefore, stations to measure the peak concentration from mobile sources should be located at the distance most likely to produce the highest concentrations. For the microscale station, the location must be between 5 and 15 meters from the major roadway. For the middle scale station, a range of acceptable distances from the major roadway is shown in table 4. This table also includes separation distances between a roadway and neighborhood or larger scale stations. These distances are based upon the data of reference 16 which illustrates that lead levels remain fairly constant after certain horizontal distances from the roadway. As depicted in the above reference, this distance is a function of the traffic volume.


Table 3_Separation Distance Between Pb Stations and Roadways (Edge of
Nearest Traffic Lane)
------------------------------------------------------------------------
Separation distance between roadways
and stations, meters
-------------------------------------
Roadway average daily traffic Neighborhood
vehicles per day Middle urban
Microscale scale regional
scale
------------------------------------------------------------------------
[le]10,000........................ 5-15 \1\>15- \1\>50
50
20,000........................... 5-15 >15-75 >75
>=40,000.......................... 5-15 >15-100 >100
------------------------------------------------------------------------
\1\ Distances should be interpolated based on traffic flow.


7.4. Spacing from trees and other considerations. Trees can provide surfaces for deposition or adsorption of Pb particles and obstruct normal wind flow patterns. For microscale and middle scale category (a) sites there must not be any tree(s) between the source of the Pb and the sampler. For neighborhood scale category (b) sites, the sampler should be at least 20 meters from the drip line of trees. The sampler must, however, be placed at least 10 meters from the drip line of trees which could be classified as an obstruction, i.e., the distance between the tree(s) and the sampler is less than the height that the tree protrudes above the sampler.

8. Particulate Matter (PM10 and PM2.5)

8.1 Vertical Placement. Although there are limited studies on the PM10 concentration gradients around roadways or other ground level sources, References 1, 2, 4, 18 and 19 of this appendix show a distinct variation in the distribution of TSP and Pb levels near roadways, TSP, which is greatly affected by gravity, has large concentration gradients, both horizontal and vertical, immediately adjacent to roads. Lead, being predominately sub-micron in size, behaves more like a gas and exhibits smaller vertical and horizontal gradients than TSP. PM10, being intermediate in size between these two extremes exhibits dispersion properties of both gas and settleable particulates and does show vertical and horizontal gradients. 30 Similar to monitoring for other pollutants, optimal placement of the sampler inlet for PM10 monitoring should be at breathing height level. However, practical factors such as prevention of vandalism, security, and safety precautions must also be considered when siting a PM10 monitor. Given these considerations, the sampler inlet for microscale PM10 monitors must be 2–7 meters above ground level. The lower limit was based on a compromise between ease of servicing the sampler and the desire to avoid re-entrainment from dusty surfaces. The upper limit represents a compromise between the desire to have measurements which are most representative of population exposures and a consideration of the practical factors noted above. Although microscale or middle scale stations are not the preferred spatial scale for PM2.5 sites, there are situations where such sites are representative of several locations within an area where large segments of the population may live or work (e.g., central business district of Metropolitan area). In these cases, the sampler inlet for such microscale PM2.5 stations must also be 2-7 meters above ground level.

For middle or larger spatial scales, increased diffusion results in vertical concentration gradients that are not as great as for the microscale. Thus, the required height of the air intake for middle or larger scales is 2–15 meters.

8.2 Spacing From Obstructions. If the sampler is located on a roof or other structure, then there must be a minimum of 2 meters separation from walls, parapets, penthouses, etc. No furnace or incineration flues should be nearby. This separation distance from flues is dependent on the height of the flues, type of waste or fuel burned, and quality of the fuel (ash content). In the case of emissions from a chimney resulting from natural gas combustion, as a precautionary measure, the sampler should be placed at least 5 meters from the chimney.

On the other hand, if fuel oil, coal, or solid waste is burned and the stack is sufficiently short so that the plume could reasonably be expected to impact on the sampler intake a significant part of the time, other buildings/locations in the area that are free from these types of sources should be considered for sampling. Trees provide surfaces for particulate desposition and also restrict airflow. Therefore, the sampler should be placed at least 20 meters from the dripline and must be 10 meters from the dripline when the tree(s) acts as an obstruction.

The sampler must also be located away from obstacles such as buildings, so that the distance between obstacles and the sampler is at least twice the height that the obstacle protrudes above the sampler except for street canyon sites. Sampling stations that are located closer to obstacles than this criterion allows should not be classified as neighborhood, urban, or regional scale, since the measurements from such a station would closely represent middle scale stations. Therefore, stations not meeting the criterion should be classified as middle scale.

There must be unrestricted airflow in an arc of at least 270° around the sampler except for street canyon sites. Since the intent of the category (a) site is to measure the maximum concentrations from a road or point source, there must be no significant obstruction between a road or point source and the monitor, even though other spacing from obstruction criteria are met. The predominant direction for the season with the greatest pollutant concentration potential must be included in the 270° arc.

8.3 Spacing From Roads. Since emissions associated with the operation of motor vehicles contribute to urban area particulate matter ambient levels, spacing from roadway criteria are necessary for ensuring national consistency in PM sampler siting.

The intent is to locate category (a) NAMS sites in areas of highest concentrations whether it be from mobile or multiple stationary sources. If the area is primarily affected by mobile sources and the maximum concentration area(s) is judged to be a traffic corridor or street canyon location, then the monitors should be located near roadways with the highest traffic volume and at separation distances most likely to produce the highest concentrations. For the microscale traffic corridor station, the location must be between 5 and 15 meters from the major roadway. For the microscale street canyon site the location must be between 2 and 10 meters from the roadway. For the middle scale station, a range of acceptable distances from the roadway is shown in Figure 2. This figure also includes separation distances between a roadway and neighborhood or larger scale stations by default. Any station, 2 to 15 meters high, and further back than the middle scale requirements will generally be neighborhood, urban or regional scale. For example, according to Figure 2, if a PM sampler is primarily influenced by roadway emissions and that sampler is set back 10 meters from a 30,000 ADT road, the station should be classified as a micro scale, if the sampler height is between 2 and 7 meters. If the sampler height is between 7 and 15 meters, the station should be classified as middle scale. If the sample is 20 meters from the same road, it will be classified as middle scale; if 40 meters, neighborhood scale; and if 110 meters, an urban scale.



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It is important to note that the separation distances shown in Figure 2 are measured from the edge of the nearest traffic lane of the roadway presumed to have the most influence on the site. In general, this presumption is an oversimplification of the usual urban settings which normally have several streets that impact a given site. The effects of surrounding streets, wind speed, wind direction and topography should be considered along with Figure 2 before a final decision is made on the most appropriate spatial scale assigned to the sampling station.

8.4 Other Considerations. For those areas that are primarily influenced by stationary source emissions as opposed to roadway emissions, guidance in locating these areas may be found in the guideline document Optimum Network Design and Site Exposure Criteria for Particulate Matter. 2 9

Stations should not be located in an unpaved area unless there is vegetative ground cover year round, so that the impact of wind blown dusts will be kept to a minimum.

9. Probe Material and Pollutant Sample Residence Time

For the reactive gases, SO2, NO2, and O3, special probe material must be used for point analyzers. Studies20–24 have been conducted to determine the suitability of materials such as polypropylene, polyethylene, polyvinyl chloride, Tygon, aluminum, brass, stainless steel, copper, Pyrex glass and Teflon for use as intake sampling lines. Of the above materials, only Pyrex glass and Teflon have been found to be acceptable for use as intake sampling lines for all the reactive gaseous pollutants. Furthermore, the EPA 25 has specified borosilicate glass or FEP Teflon as the only acceptable probe materials for delivering test atmospheres in the determination of reference or equivalent methods. Therefore, borosilicate glass, FEP Teflon, or their equivalent must be used for existing and new NAMS or SLAMS.

20–29See References at end of this appendix.

For VOC monitoring at those SLAMS designated as PAMS, FEP teflon is unacceptable as the probe material because of VOC adsorption and desorption reactions on the FEP teflon. Borosilicate glass, stainless steel, or its equivalent are the acceptable probe materials for VOC and carbonyl sampling. Care must be taken to ensure that the sample residence time is 20 seconds or less.

No matter how nonreactive the sampling probe material is initially, after a period of use reactive particulate matter is deposited on the probe walls. Therefore, the time it takes the gas to transfer from the probe inlet to the sampling device is also critical. Ozone in the presence of NO will show significant losses even in the most inert probe material when the residence time exceeds 20 seconds. 26 Other studies27–28 indicate that a 10-second or less residence time is easily achievable. Therefore, sampling probes for reactive gas monitors at SLAMS or NAMS must have a sample residence time less than 20 seconds.

10. Photochemical Assessment Monitoring Stations (PAMS)

10.1 Horizontal and Vertical Placement. The probe or at least 80 percent of the monitoring path must be located 3 to 15 meters above ground level. This range provides a practical compromise for finding suitable sites for the multipollutant PAMS. The probe or at least 90 percent of the monitoring path must be at least 1 meter vertically or horizontally away from any supporting structure, walls, parapets, penthouses, etc., and away from dusty or dirty areas.

10.2 Spacing From Obstructions. The probe or at least 90 percent of the monitoring path must be located away from obstacles and buildings such that the distance between the obstacles and the probe or the monitoring path is at least twice the height that the obstacle protrudes above the probe or monitoring path. There must be unrestricted airflow in an arc of at least 270° around the probe inlet. Additionally, the predominant wind direction for the period of greatest pollutant concentration (as described for each site in section 4.2 of appendix D) must be included in the 270° arc. If the probe is located on the side of the building, 180° clearance is required. A monitoring path must be clear of all trees, brush, buildings, plumes, dust, or other optical obstructions, including potential obstructions that may move due to wind, human activity, growth of vegetation, etc. Temporary optical obstructions, such as rain, particles, fog, or snow, should be considered when siting an open path analyzer. Any of these temporary obstructions that are of sufficient density to obscure the light beam will affect the ability of the open path analyzer to continuously measure pollutant concentrations.

Special consideration must be devoted to the use of open path analyzers due to their inherent potential sensitivity to certain types of interferences, or optical obstructions. While some of these potential interferences are comparable to those to which point monitors are subject, there are additional sources of potential interferences which are altogether different in character. Transient, but significant obscuration of especially longer measurement paths could be expected to occur as a result of certain prevailing meteorological conditions (e.g., heavy fog, rain, snow) and/or aerosol levels that are of a sufficient density to prevent the open path analyzer's light transmission. If certain compensating measures are not otherwise implemented at the onset of monitoring (e.g., shorter path lengths, higher light source intensity), data recovery during periods of greatest primary pollutant potential could be compromised. For instance, if heavy fog or high particulate levels are coincident with periods of projected NAAQS-threatening pollutant potential, the representativeness of the resulting data record in reflecting maximum pollutant concentrations may be substantially impaired despite the fact that the site may otherwise exhibit an acceptable, even exceedingly high overall valid data capture rate. (continued)