CCLME.ORG - DIVISION 4.5. ENVIRONMENTAL HEALTH STANDARDS FOR THE MANAGEMENT OF HAZARDOUS WASTE
Loading (50 kb)...'
(continued)
QA 29.8ml 1
CA = ------ X ------ X --------
MW mmole 2 X 10 [FN-6]M [FN3]


where C (in parts per million) is the concentration of material A in head space vapor, Q (in milligrams) is the quantity of material A in sampling syringe and MW (in milligrams per millimole) is the molecular weight of material A. Where an acute inhalation LC 50 is not available, an LC 50 measured for another time (t) may be converted to an eight-hour value with the following equation:
Eight-hour LC 50 = (t/8) x (t-hour LC 50).
(c) A waste containing one or more materials which exhibit the characteristic of toxicity because the materials have either of the properties specified in subsection (a)(3) or (a)(4) of this section may be classified as nonhazardous pursuant to section 66260.200 if the waste does not exhibit any other characteristic of this article and is not listed in article 4 of this chapter and the calculated oral LD 50 of the waste mixture is greater than 2,500 milligrams per kilogram and the calculated dermal LD 50 is greater than 4,300 milligrams per kilogram by the following equation:

where %A x is the weight percent of each component in the waste mixture and [FNT]A X is the acute oral or dermal LD 50 or the acute oral LD LO of each component.

Note: Authority cited: Sections 25141, 25159, 58004 and 58012, Health and Safety Code. Reference: Sections 25117, 25120.2, 25141, 25159 and 25159.5, Health and Safety Code and 40 CFR Section 261.24.





s 66261.30. General.
(a) A waste is a RCRA hazardous waste if it is listed in this article, unless it has been excluded from this list pursuant to 40 CFR sections 260.20 and 260.22 or is categorized as a non-RCRA hazardous waste pursuant to section 66261.101. Wastes shall only be listed in this article if they are listed in 40 CFR Part 261 Subpart D.
(b) The Department will indicate the USEPA Administrator's basis for listing the classes or types of wastes listed in this article by employing one or more of the following Hazard Codes:
Ignitable Waste (I)
Corrosive Waste (C)
Reactive Waste (R)
Acute Hazardous Waste (H)
Toxic Waste (T)

Appendix VII of this chapter identifies the constituent which caused the USEPA Administrator to list the waste as a Toxic Waste (T) as included in sections 66261.31 and 66261.32.
(c) Each RCRA hazardous waste listed in this article is assigned an EPA Hazardous Waste Number which precedes the name of the waste. This number shall be used in complying with the notification requirements of Health and Safety Code section 25153.6 and certain recordkeeping and reporting requirements under chapters 12 through 15, 18, and 20 of this division.

Note: Authority cited: Sections 208, 25141 and 25159, Health and Safety Code. Reference: Sections 25117, 25120.2, 25141, 25159 and 25159.5, Health and Safety Code and 40 CFR Section 261.30.





s 66261.31. Hazardous Wastes from Non-Specific Sources.
(a) The following wastes are listed hazardous wastes from non-specific sources unless they are excluded pursuant to 40 CFR sections 260.20 and 260.22:
EPA Hazard
Hazardous
Waste No. Hazardous Waste Code
F001....... the following spent halogenated solvents used in (T)
degreasing: Tetrachloroethylene, trichloroethylene,
methylene chloride, 1,1,1-trichloroethane, carbon
tetrachloride, and chlorinated fluorocarbons; all
spent solvent mixtures/blends used in degreasing
containing, before use, a total of ten percent or more
(by volume) of one or more of the above halogenated
solvents or those solvents listed in F002, F004, and
F005; and still bottoms from the recovery of these
spent solvents and spent solvent mixtures;
F002....... the following spent halogenated solvents: (T)
tetrachloroethylene, methylene chloride,
trichloroethylene, 1,1,1-trichloroethane,
chlorobenzene, 1,1,2-trichloro-1,2,2-trifluoroethane,
ortho-dichlorobenzene, trichlorofluoromethane, and
1,1,2-trichloroethane; all spent solvent
mixtures/blends containing, before use, a total of ten
percent or more (by volume) of one or more of the
above halogenated solvents or those listed in F001,
F004, or F005; and still bottoms from the recovery of
these spent solvents and spent solvent mixtures;
F003....... the following spent non-halogenated solvents: (I)
[FNa1]
xylene, acetone, ethyl acetate, ethyl benzene, ethyl
ether, methyl isobutyl ketone, n-butyl alcohol,
cyclohexanone, and methanol; all spent solvent
mixtures/blends containing, before use, only the above
spent non-halogenated solvents; and all spent solvent
mixtures/blends containing, before use, one or more of
the above non-halogenated solvents, and, a total of
ten percent or more (by volume) of one or more of
those solvents listed in F001, F002, F004, and F005;
and still bottoms from the recovery of these spent
solvents and spent solvent mixtures;
F004....... the following spent non-halogenated solvents: (T)
cresols and cresylic acid, and nitrobenzene; all spent
solvent mixtures/blends containing, before use, a
total of ten percent or more (by volume) of one or
more of the above non-halogenated solvents or those
solvents listed in F001, F002, and F005; and still
bottoms from the recovery of these spent solvents and
spent solvent mixtures;
F005....... the following spent non-halogenated solvents: (I,T)
toluene, methyl ethyl ketone, carbon disulfide,
isobutanol, pyridine, benzene, 2-ethoxyethanol, and
2-nitropropane; all spent solvent mixtures/blends
containing, before use, a total of ten percent or more
(by volume) of one or more of the above
non-halogenated solvents or those solvents listed in
F001, F002, or F004; and still bottoms from the
recovery of these spent solvents and spent solvent
mixtures;
F006....... wastewater treatment sludges from electroplating (T)
operations except from the following processes: (1)
sulfuric acid anodizing of aluminum; (2) tin plating
on carbon steel; (3) zinc plating (segregated basis)
on carbon steel; (4) aluminum or zinc-aluminum plating
on carbon steel; (5) cleaning/stripping associated
with tin, zinc and aluminum plating on carbon steel;
and (6) chemical etching and milling of aluminum;
F007....... spent cyanide plating bath solutions from (R,T)
electroplating operations;
F008....... plating bath residues from the bottom of plating (R,T)
baths from electroplating operations where cyanides are
used in the process;
F009....... spent stripping and cleaning bath solutions from (R,T)
electroplating operations where cyanides are used in the
process;
F010....... quenching bath residues from oil baths from metal (R,T)
heat treating operations where cyanides are used in the
process;
F011....... spent cyanide solutions from salt bath pot (R,T)
cleaning from metal heat treating operations;
F012....... quenching waste water treatment sludges from (T)
metal heat treating operations where cyanides are used
in the process;
F019....... wastewater treatment sludges from the chemical (T)
conversion coating of aluminum except from zirconium
phosphating in aluminum can washing when such
phosphating is an exclusive conversion coating
process;
F020....... wastes (except wastewater and spent carbon from (H) H)
hydrogen chloride purification) from the production or
manufacturing use (as a reactant, chemical
intermediate, or component in a formulating process)
of tri- or tetrachlorophenol, or of intermediates used
to produce their pesticide derivatives; (This listing
does not include wastes from the production of
Hexachlorophene from highly purified
2,4,5-trichlorophenol.)
F021....... wastes (except wastewater and spent carbon from (H)
hydrogen chloride purification) from the production or
manufacturing use (as a reactant, chemical
intermediate, or component in a formulating process)
of pentachlorophenol, or of intermediates used to
produce its derivatives;
F022....... wastes (except wastewater and spent carbon from (H)
hydrogen chloride purification) from the manufacturing
use (as a reactant, chemical intermediate, or
component in a formulating process) of tetra-, penta-,
or hexachlorobenzenes under alkaline conditions;
F023....... wastes (except wastewater and spent carbon from (H)
hydrogen chloride purification) from the production of
materials on equipment previously used for the
production or manufacturing use (as a reactant,
chemical intermediate, or component in a formulating
process) of tri- and tetrachlorophenols; (This listing
does not include wastes from equipment used only for
the production or use of Hexachlorophene from highly
purified 2,4,5-trichlorophenol.)
F024....... process wastes, including but not limited to, (T)
distillation, residues, heavy ends, tars, and reactor
clean-out wastes, from the production of certain
chlorinated aliphatic hydrocarbons by free radical
catalyzed processes. These chlorinated aliphatic
hydrocarbons are those having carbon chain lengths
ranging from one to and including five, with varying
amounts and positions of chlorine substitution; (This
listing does not include wastewaters, wastewater
treatment sludges, spent catalysts, and wastes listed
in section 66261.31 or 66261.32.)
F025....... condensed light ends, spent filters and filter aids, (T)
and spent dessicant wastes from the production of
certain chlorinated aliphatic hydrocarbons, by free
radical catalyzed processes. These chlorinated
aliphatic hydrocarbons are those having carbon chain
lengths ranging from one to and including five, with
varying amounts and positions of chlorine
substitution;
F026....... wastes (except wastewater and spent carbon from (H)
hydrogen chloride purification) from the production of
materials on equipment previously used for the
manufacturing use (as a reactant, chemical
intermediate, or component in a formulating process)
of tetra-, penta-, or hexachlorobenzene under alkaline
conditions;
F027....... discarded unused formulations containing tri-, (H)
tetra-, or pentachlorophenol or discarded unused
formulations containing compounds derived from these
chlorophenols; (This listing does not include
formulations containing Hexachlorophene synthesized
from prepurified 2,4,5-trichlorophenol as the sole
component.)
F028....... residues resulting from the incineration or (T)
thermal treatment of soil contaminated with EPA
Hazardous Waste Nos. F020, F021, F022, F023, F026, and
F027; F032 wastewaters (except those that have not
come into (T) contact with process contaminants),
process residuals, preservative drippage, and spent
formulations from wood preserving processes generated
at plants that currently use or have previously used
chlorophenolic formulations (except potentially
cross-contaminated wastes that have had the F032 waste
code deleted in accordance with section 66261.35 of
this chapter or potentially cross-contaminated wastes
that are otherwise currently regulated as hazardous
wastes (i.e., F034 or F035), and where the generator
does not resume or initiate use of chorophenolic
formulations). This listing does not include K001
bottom sediment sludge from the treatment of waste
water from wood preserving processes that use creosote
and/or pentachlorophenol;
F034....... Wastewaters (except those that have not come into (T)
contact with process contaminants), process residuals,
preservative drippage, and spent formulations from
wood preserving processes generated at plants that use
creosote formulations. This listing does not include
K001 bottom sediment sludge from the treatment of
wastewater from wood preserving processes that use
creosote and/or pentachlorophenol;
F035....... Wastewaters (except those that have not come into (T)
contact with process contaminants), process residuals,
preservative drippage, and spent formulations from
wood preserving processes generated at plants that use
inorganic preservatives containing arsenic or
chromium. This listing does not include K001 bottom
sediment sludge from the treatment of wastewater from
wood preserving processes that use creosote and/or
pentachlorophenol.
F037....... petroleum refinery primary oil/water/solids (T)
separation sludge - any sludge generated from the
gravitational separation of oil/water/solids during
the storage or treatment of process wastewaters and
oily cooling wastewaters from petroleum refineries.
Such sludges include, but are not limited to, those
generated in: oil/water/solids separators; tanks and
impoundments; ditches and other conveyances; sumps;
and stormwater units receiving dry weather flow.
Sludges generated in stormwater units that do not
receive dry weather flow, sludges generated from
non-contact once-through cooling waters segregated for
treatment from other process or oily cooling waters,
sludges generated in aggressive biological treatment
units as defined in section 66261.31(b)(2) (including
sludges generated in one or more additional units
after wastewaters have been treated in aggressive
biological treatment units) and K051 wastes are not
included in this listing.
F038....... petroleum refinery secondary (emulsified) (T)
oil/water/solids separation sludge - any sludge and/or
float generated from the physical and/or chemical
separation of oil/water/solids in process wastewaters
and oily cooling wastewaters from petroleum
refineries. Such wastes include, but are not limited
to, all sludges and floats generated in: induced air
flotation (IAF) units; tanks and impoundments; and all
sludges generated in dissolved air flotation (DAF)
units. Sludges generated in stormwater units that do
not receive dry weather flow, sludges generated from
non-contact once-through cooling waters segregated for
treatment from other process or oily cooling waters,
sludges and floats generated in aggressive biological
treatment units as defined in section 66261.31(b)(2)
(including sludges and floats generated in one or more
additional units after wastewaters have been treated
in aggressive biological treatment units) and F037,
K048, and K051 wastes are not included in this
listing.
F039....... leachate (liquids that have percolated through (T)
land disposed wastes) resulting from the disposal of
more than one restricted waste classified as hazardous
under article 4 of this chapter. (Leachate resulting
from the disposal of one or more of the following EPA
Hazardous Wastes and no other hazardous wastes retains
its EPA hazardous waste number(s): F020, F021, F022,
F026, F027, and/or F028.)

[FNa1] (I) specifies mixtures containing ignitable constituents.
[FNa2] (I,T) specifies mixtures containing ignitable and toxic constituents.
(b) Listing Specific Definitions:
(1) For the purposes of the F037 and F038 listings, oil/water/solids is defined as oil and/or water and/or solids.
(2)(A) For the purposes of the F037 and F038 listings, aggressive biological treatment units are defined as units which employ one of the following four treatment methods: activated sludge; trickling filter; rotating biological contactor for the continuous accelerated biological oxidation of wastewaters; or high-rate aeration. High-rate aeration is a system of surface impoundments or tanks, in which intense mechanical aeration is used to completely mix the wastes, enhance biological activity, and:
1. The unit employs a minimum of six horsepower per million gallons of treatment volume; and
2. a. The hydraulic retention time of the unit is no longer than five days; or
b. The hydraulic retention time is no longer than 30 days and the unit does not generate a sludge that is a hazardous waste by the Toxicity Characteristic.
(B) Generators and treatment, storage and disposal facilities have the burden of proving that sludges generated or managed by the generator or facility are exempt from listing as F037 and F038 wastes under this definition. Generators and treatment, storage anddisposal facilities shall maintain, in the facility operating or other onsite records, documents and data sufficient to prove that:
1. The unit is an aggressive biological treatment unit as defined in this subsection; and
2. The sludges sought to be exempted from the definitions of F037 and/or F038 wastes were actually generated in the aggressive biological treatment unit.
(3)(A) For the purposes of the F037 listing, sludges are considered to be generated at the moment of deposition in the unit, where deposition is defined as at least a temporary cessation of lateral particle movement.
(B) For the purposes of the F038 listing:
1. Sludges are considered to be generated at the moment of deposition in the unit, where deposition is defined as at least a temporary cessation of lateral particle movement; and
2. Floats are considered to be generated at the moment of formation in the top of the unit.

Note: Authority cited: Section 58012, Governor's Reorganizational Plan Number 1 of 1991; and sections 25140, 25141, 25150, 25159, 25159.5 and 25179.6, Health and Safety Code. Reference: Sections 25117, 25120.2, 25150, 25159 and 25159.5, Health and Safety Code; and 40 CFR Section 261.31.





s 66261.32. Hazardous Wastes from Specific Sources.
The following wastes are listed hazardous wastes from specific sources unless they are excluded pursuant to 40 CFR sections 260.20 and 260.22:
_______________________________________________________________________________
Industry and EPA
Hazardous Hazard
Waste No. Hazardous Waste Code
_______________________________________________________________________________
Wood preservation:
K001................................ bottom sediment sludge from the (T)
treatment of
wastewaters from wood preserving
processes that use creosote and/or
pentachlorophenol;
Inorganic pigments:
K002................................ wastewater treatment sludge from (T)
the production
of chrome yellow and orange
pigments;
K003................................ wastewater treatment sludge from (T)
the production
of molybdate orange pigments;
K004................................ wastewater treatment sludge from (T)
the production
of zinc yellow pigments;
K005................................ wastewater treatment sludge from (T)
the production
of chrome green pigments;
K006................................ wastewater treatment sludge from (T)
the production
of chrome oxide green pigments
(anhydrous and hydrated);
K007................................ wastewater treatment sludge from (T)
the production
of iron blue pigments;
K008................................ oven residue from the production (T)
of chrome oxide
green pigments;

Organic chemicals:
K009 distillation bottoms from the production of (T)
acetaldehyde from ethylene;
K010 distillation side cuts from the production of (T)
acetaldehyde from ethylene;
K011 bottom stream from the wastewater stripper in the (R,T)
production of acrylonitrile;
K013 bottom stream from the acetonitrile column in the (R,T)
production of acrylonitrile;
K014 bottoms from the acetonitrile purification column (T)
in the production of acrylonitrile;
K015 still bottoms from the distillation of benzyl (T)
chloride;
K016 heavy ends or distillation residues from the (T)
production of carbon tetrachloride;
K017 heavy ends (still bottoms) from the purification (T)
column in the production of epichlorohydrin;
K018 heavy ends from the fractionation column in ethyl (T)
chloride production;
K019 heavy ends from the distillation of ethylene (T)
dichloride in ethylene dichloride production;
K020 heavy ends from the distillation of vinyl chloride (T)
in vinyl chloride monomer production;
K021 aqueous spent antimony catalyst waste from (T)
fluoromethanes production;
K022 distillation bottom tars from the production of (T)
phenol/acetone from cumene;
K023 distillation light ends from the production of (T)
phthalic anhydride from naphthalene;
K024 distillation bottoms from the production of (T)
phthalic anhydride from naphthalene;
K093 distillation light ends from the production of (T)
phthalic anhydride from ortho-xylene;
K094 distillation bottoms from the production of (T)
phthalic anhydride from ortho-xylene;
K025 distillation bottoms from the production of (T)
nitrobenzene by the nitration of benzene;
K026 stripping still tails from the production of (T)
methyl ethyl pyridines;
K027 centrifuge and distillation residues from toluene (R,T)
diisocyanate production;
K028 spent catalyst from the hydrochlorinator reactor (T)
in the production of 1,1,1-trichloroethane;
K029 waste from the product steam stripper in the (T)
production of 1,1,1-trichloroethane;
K095 distillation bottoms from the production of (T)
1,1,1-trichloroethane;
K096 heavy ends from the heavy ends column from the (T)
production of 1,1,1-trichloroethane;
K030 column bottoms or heavy ends from the combined (T)
production of trichloroethylene and perchloroethylene;
K083 distillation bottoms from aniline production; (T)
K103 process residues from aniline extraction from (T)
the production of aniline;
K104 combined wastewater streams generated from (T)
nitrobenzene/aniline production;
K085 distillation or fractionation column bottoms from (T)
the production of chlorobenzenes;
K105 separated aqueous stream from the reactor product (T)
washing step in the production of chlorobenzenes;
K107 column bottoms from product separation (C,T)
from the production of 1,1-dimethylhydrazine (UDMH) from carboxylic acid hydrazines;
K108 condensed column overheads from product (I,T)
separation and condensed reactor vent gases from the production of 1,1- dimethylhydrazine (UDMH) from carboxylic acid hydrazides;
K109 spent filter cartridges from product (T)
purification from the production of 1,1-dimethylhydrazine (UDMH) from carboxylic acid hydrazides;
K110 condensed column overheads from intermediate (T)
separation from the production of 1,1-dimethylhydrazine (UDMH) from carboxylic acid hydrazides;
K111 product washwaters from the production of (C,T)
dinitrotoluene via nitration of toluene;
K112 reaction by-product water from the drying column (T)
in the production of toluenediamine via hydrogenation of dinitrotoluene;
K113 condensed liquid light ends from the purification (T)
of toluenediamine in the production of toluenediamine via hydrogenation of dinitrotoluene;
K114 vicinals from the purification of toluenediamine (T)
in the production of toluenediamine via hydrogenation of dinitrotoluene;
K115 heavy ends from the purification of toluenediamine (T)
in the production of toluenediamine via hydrogenation of dinitrotoluene;
K116 organic condensate from the solvent recovery (T)
column in the production of toluene diisocyanate via phosgenation of toluenediamine;
K117 wastewater from the reactor vent gas scrubber in (T)
the production of ethylene dibromide via bromination of ethylene;
K118 spent absorbent solids from purification of (T)
ethylene dibromide in the production of ethylene dibromide via bromination of ethylene;
K136 still bottoms from the purification of ethylene (T)
dibromide in the production of ethylene dibromide via bromination of ethylene;
K149 Distillation bottoms from the production of (T)
alpha- (or methyl-) chlorinated toluenes, ring-chlorinated toluenes, benzoyl chlorides, and compounds with mixtures of these functional groups. (This waste does not include still bottoms from the distillation of benzyl chloride).
K150 Organic residuals, excluding spent carbon (T)
adsorbent, from the spent chlorine gas and hydrochloric acid recovery processes associated with the production of alpha- (or methyl-) chlorinated toluenes, ring- chlorinated toluenes, benzoyl chlorides, and compounds with mixtures of these functional groups.
K151 Wastewater treatment sludges, excluding (T)
neutralization and biological sludges, generated during the treatment of wastewaters from the production of alpha- (or methyl-) chlorinated toluenes, ring-chlorinated toluenes, benzoyl chlorides, and compounds with mixtures of these functional groups.
K156 Organic waste (including heavy ends, still (T)
bottoms, light ends, spent solvents, filtrates, and decantates) from the production of carbamates and carbamoyl oximes. (This listing does not apply to wastes generated from the manufacture of 3-iodo-2-propynyl n-butylcarbamate.)
K157 Wastewaters (including scrubber waters, (T)
condenser waters, washwaters, and separation waters) from the production of carbamates and carbamoyl oximes (This listing does not apply to wastes generated from the manufacture of 3-iodo-2-propynyl n-butylcarbamate.).
K158 Bag house dusts and filter/separation solids (T)
from the production of carbamates and carbamoyl oximes. (This listing does not apply to wastes generated from the manufacture of 3-iodo-2-propynyl n-butylcarbamate.).
K159 Organics from the treatment of thiocarbamate (T)
wastes.
K161 Purification solids (including filtration, (T)
evaporation, and centrifugation solids), bag house dust and floor sweepings from the production of dithiorcarbamate acids and their salts. (This listing does not include K125 or K126.)
K174 Wastewater treatment sludges from the (T)
production of ethylene dichloride or vinyl chloride monomer (including sludges that result from commingled ethylene dichloride or vinyl chloride monomer wastewater and other wastewater), unless the sludges meet the following conditions: (i) they are disposed of in a RCRA subtitle C or non-hazardous landfill licensed or permitted by the state or federal government; (ii) they are not otherwise placed on the land prior to final disposal; and (iii) the generator maintains documentation demonstrating that the waste was either disposed of in an on-site landfill or consigned to a transporter or disposal facility that provided a written commitment to dispose of the waste in an off-site landfill. Respondents in any action brought to enforce the requirements of this division must, upon a showing by the government that the respondent managed wastewater treatment sludges from the production of vinyl chloride monomer or ethylene dichloride, demonstrate that they meet the terms of the exclusion set forth above. In doing so, they must provide appropriate documentation (e.g., contracts between the generator and the landfill owner/operator, invoices documenting delivery of waste to landfill, etc.) that the terms of the exclusion were met.
K175 Wastewater treatment sludges from the T
production of vinyl chloride monomer using mercuric chloride catalyst in an acetylene-based process.
Inorganic chemicals:
K071 brine purification muds from the mercury cell (T)
process in chlorine production, where separately prepurified brine is not used;
K073 chlorinated hydrocarbon waste from the (T)
purification step of the diaphragm cell process using graphite anodes in chlorine production;
K106 wastewater treatment sludge from the mercury cell (T)
process in chlorine production;
Pesticides: K031 by-product salts generated in the production of (T)
MSMA and cacodylic acid;
K032 wastewater treatment sludge from the production (T)
of chlordane;
K033 wastewater and scrub water from the chlorination (T)
of cyclopentadiene in the production of chlordane;
K034 filter solids from the filtration of (T)
hexachlorocyclopentadiene in the production of chlordane;
K097 vacuum stripper discharge from the chlordane (T)
chlorinator in the production of chlordane;
K035 wastewater treatment sludges generated in the (T)
production of creosote;
K036 still bottoms from toluene reclamation (T)
distillation in the production of disulfoton;
K037 wastewater treatment sludges from the production (T)
of disulfoton;
K038 wastewater from the washing and stripping of (T)
of disulfoton;
K039 filter cake from the filtration of (T)
diethylphosphorodithioic acid in the production of phorate;
K040 wastewater treatment sludge from the production (T)
of phorate;
K041 wastewater treatment sludge from the production (T)
of toxaphene;
K098 untreated process wastewater from the production (T)
of toxaphene;
K042 heavy ends or distillation residues from the (T)
distillation of tetrachlorobenzene in the production of 2,4,5-T;
K043 2,6-Dichlorophenol waste from the production (T)
of 2,4-D;
K099 untreated wastewater from the production (T)
of 2,4-D;
K123 process wastewater (including supernates, (T)
filtrates, and washwaters) from the production of ethylenebisdithiocarbamic acid and its salt;
K124 reactor vent scrubber water from the production (C,T)
of ethylenebisdithiocarbamic acid and its salts;
K125 filtration, evaporation, and centrifugation (T)
solids from the production of ethylenebisdithiocarbamic acid and its salts;
K126 baghouse dust and floor sweepings in milling and (T)
packaging operations from the production or formulation of ethylenebisdithiocarbamic acid and its salts;
K131 wastewater from the reactor and spent sulfuric acid (C,T)
from the acid dryer from the production of methyl bromide;
K132 spent absorbent and wastewater separator solids (T)
from the production of methyl bromide;
Explosives:
K044 wastewater treatment sludges from the (R)
manufacturing and processing of explosives;
K045 spent carbon from the treatment of wastewater (R)
containing explosives;
K046 wastewater treatment sludges from the (T)
manufacturing, formulation and loading of lead-based initiating compounds;
K047 pink/red water from TNT operations; (R)
Petroleum refining:
K048 dissolved air flotation (DAF) float from the (T)
petroleum refining industry;
K049 slop oil emulsion solids from the petroleum (T)
refining industry;
K050 heat exchanger bundle cleaning sludge from the (T)
petroleum refining industry;
K051 API separator sludge from the petroleum refining (T)
industry;
K052 tank bottoms (leaded) from the petroleum refining (T)
industry;
Iron and steel:
K061 emission control dust/sludge from the primary (T)
production of steel in electric furnaces;
K062 spent pickle liquor generated by steel finishing (C,T)
operations of facilities within the iron and steel industry (SIC Codes 331 and 332);
Primary copper:
K064 acid plant blowdown slurry/sludge resulting from (T)
the thickening of blowdown slurry from primary copper production;
Primary lead:
K065 surface impoundment solids contained in and (T)
dredged from surface impoundments at primary lead smelting facilities;
Primary zinc:
K066 sludge from treatment of process wastewater (T)
and/or acid plant blowdown from primary zinc production;
Primary aluminum:
K088 spent potliners from primary aluminum reduction; (T)
Ferro alloys:
K090 emission control dust or sludge from (T)
ferrochromium-silicon production;
K091 emission control dust or sludge from (T)
ferrochromium production;
Secondary lead:
K069 emission control dust/sludge from secondary lead (T)
smelting; (Note, this listing has been stayed administratively for sludge generated from secondary acid scrubber systems. The stay will remain in effect until further administrative action is taken. Further administrative action will be taken after the U.S. EPA publishes a notice of action in the /Federal Register and the Department adopts regulations making this listing effective.)
K100 waste leaching solution from acid leaching of (T)
emission control dust/sludge from secondary lead smelting;
Veterinary pharmaceuticals:
K084 wastewater treatment sludges generated during the (T)
production of veterinary pharmaceuticals from arsenic or organo-arsenic compounds;
K101 distillation tar residues from the distillation (T)
of aniline-based compounds in the production of veterinary pharmaceuticals from arsenic or organo-arsenic compounds;
K102 residue from the use of activated carbon for (T)
decolorization in the production of veterinary pharmaceuticals from arsenic or organo-arsenic compounds;
Ink formulation:
K086 solvent washes and sludges, caustic washes and (T)
sludges, or water washes and sludges from cleaning tubs and equipment used in the formulation of ink from pigments, driers, soaps, and stabilizers containing chromium and lead;
Coking:
K060 ammonia still lime sludge from coking operations; (T)
K087 decanter tank tar sludge from coking operations. (T)
K141 process residues from the recovery of coat tar, (T)
including, but not limited to, collecting sump residues from the production of coke from coal or the recovery of coke by-products produced from coal. This listing does not include K087 (decanter tank tar sludges from coking operations).
K142 tar storage tank residues from the production of (T)
coke from the coal or from the recovery of coke by-products produced from coal.
K143 process residues from the recovery of light oil, (T)
including, but not limited to, those generated in stills, decanters, and wash oil recovery units from the recovery of coke by-products produced from coal.
K144 wastewater sump residues from light oil refining, (T)
including, but not limited to, intercepting or contamination sump sludges from the recovery of coke by-products produced from coal.
K145 residues from naphthalene collection and recovery (T)
operations from the recovery of coke by-products produced from coal.
K147 tar storage tank residues from coal tar refining. (T)
K148 residues from coal tar distillation, including but (T)
not limited to, still bottoms.

Note: Authority cited: Sections 25150, 25159, 25170, 25250.22 and 58012, Health and Safety Code. Reference: Sections 25117, 25120.2, 25150, 25159 and 25159.5, Health and Safety Code and 40 CFR Section 261.32.





s 66261.33. Discarded Commercial Chemical Products, Off-Specification Species, Container Residues, and Spill Residues Thereof.
The following materials or items are hazardous wastes if and when they are discarded or intended to be discarded as described in section 66261.2(b):
(a) any commercial chemical product, or manufacturing chemical intermediate having the generic name listed in subsection (e) or (f) of this section. The phrase "commercial chemical product or manufacturing chemical intermediate having the generic name listed in . . ." refers to a chemical substance which is manufactured or formulated for commercial or manufacturing use which consists of the commercially pure grade of the chemical, any technical grades of the chemical that are produced or marketed, and all formulations in which the chemical is the sole active ingredient. It does not refer to a material, such as a manufacturing process waste, that contains any of the substances listed in subsection (e) or (f) of this section. Where a manufacturing process waste is deemed to be a hazardous waste because it contains a substance listed in subsection (e) or (f) of this section, such waste will be listed in either section 66261.31 or 66261.32 or will be identified as a hazardous waste by the characteristics set forth in article 3 of this chapter;
(b) any off-specification commercial chemical product or manufacturing chemical intermediate which, if it met specifications, would have the generic name listed in subsection (e) or (f) of this section;
(c) any residue remaining in a container or in an inner liner removed from a container that has held any commercial chemical product or manufacturing chemical intermediate having the generic name listed in subsections (e) or (f) of this section, unless the container is empty as defined in section 66261.7(b) of this chapter;
(d) any residue or contaminated soil, water or other debris resulting from the cleanup of a spill into or on any land or water of any commercial chemical product or manufacturing chemical intermediate having the generic name listed in subsection (e) or (f) of this section, or any residue or contaminated soil, water or other debris resulting from the cleanup of a spill, into or on any land or water, of any off-specification chemical product and manufacturing chemical intermediate which, if it met specifications, would have the generic name listed in subsection (e) or (f) of this section;
(e) the following commercial chemical products, manufacturing chemical intermediates or off-specification commercial chemical products or manufacturing chemical intermediates referred to in subsections (a) through (d) of this section, are Acute Hazardous Wastes (H). The primary hazardous properties of these materials have been indicated by the letters T (Toxicity), and R (Reactivity). Absence of a letter indicates that the compound only is listed for acute toxicity. These wastes and their corresponding EPA hazardous waste numbers are:

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EPA
Hazardous Chemical
Waste No. Abstracts No. Substances
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P023 107-20-0
P002 591-08-2
P057 640-19-7
P058 62-74-8
P002 591-08-2
P003 107-02-8
P070 116-06-3
P023 1646-88-4
P004 309-00-2
P005 107-18-6
P006 20859-73-8
P007 2763-96-4
P008 504-24-5
P009 131-74-8
P119 7803-55-6
P099 506-61-6
P010 7778-39-4
P012 1327-53-3
P011 1303-28-2
P011 1303-28-2
P012 1327-53-3
P038 692-42-2
P036 696-28-6
P054 151-56-4
P067 75-55-8
P013 542-62-1
P024 106-47-8
P077 100-01-6
P028 100-44-7
P042 51-43-4
(methylamino)ethyl]-, (R)-
P046 122-09-8
dimethyl-
P014 108-98-5
P127 1563-66-2
dimethyl-, methylcarbamate.
P188 57-64-7
with (3aS-cis)-1,2,3,3a,8,
8a-hexahydro-1,3a,8-trimethyl-
pyrrolo [2,3-b]indol-
5-yl methylcarbamate ester (1:1).
P001

(3-oxo-1-phenylbutyl)-, and salts
when present at concentrations
greater than 0.3
P028 100-44-7
P015 7440-41-7
P017 598-31-2
P018 357-57-3
P045 39196-18-4
(methylthio)-, o-[(methylamino)
carbonyl] oxime
P021 592-01-8
P189 55285-14-8
thio]methyl-,2,3-dihydro-2,2-
dimethyl- 7-benzofuranyl ester
P191 644-64-4
[(dimethyl-amino)carbonyl]-
5-methyl-1H-pyrazol-3-yl ester.
P192 119-38-0
(1-methylethyl)-1H-pyrazol-5-yl ester.
P190 1129-41-5
ester.
P127 1536-66-2
P022 75-15-0
P095 75-44-5
P189 55285-14-8
P023 107-20-0
P024 106-47-8
P026 5344-82-1
P027 542-76-7
P029 544-92-3
P202 64-00-6
P030
otherwise specified
P031 460-19-5
P033 506-77-4
P034 131-89-5
P016 542-88-1
P036 696-28-6
P037 60-57-1
P038 692-42-2
P041 311-45-5
P040 297-97-2
P043 55-91-4
P004 309-00-2
10,10-hexachloro-1,4,4a,5,8,8a-
hexahydro-,(1alpha,4alpha,4abeta,
5alpha,8alpha,8abeta)-
P060 465-73-6
1,2,3,4,10,10-hexachloro-1,4,4a,5,8,8a-
hexahydro-, (1alpha,4alpha,4abeta,
5beta,8beta,8abeta)-
P037 60-57-1
rene,3,4,5,6,9,9-hexachloro-
la,2,2a,3,6,6a,7,7a-octahydro-,
(1aalpha,2beta,2aalpha,3beta,6beta,6a
alpha, 7beta,7aalpha)-
P051
3,4,5,6,9,9-hexachloro-
1a,2,2a,3,6,6a,7,7a- octahydro-,
(1aalpha,2beta,2abeta,3alpha,6
alpha,6abeta,7beta,7aalpha)-, and
metabolites
P191 644-64-4
P044 60-51-5
P046 122-09-8
P047
P048 51-28-5
P020 88-85-7
P085 152-16-9
P111 107-49-3
P039 298-04-4
P049 541-53-7
P185 26419-73-8
dimethyl-, O-[(methylamino)-
carbonyl]oxime.
P050 115-29-7
P088 145-73-3
P051 72-20-8
P051 72-20-8
P042 51-43-4
P031 460-19-5
P066 16752-77-5
carbonyl] oxy]-, methyl ester
P194 23135-22-0
N-[[(methylamino) carbonyl]oxy]-2-
oxo-, methyl ester.
P101 107-12-0
P054 151-56-4
P097 52-85-7
P056 7782-41-4
P057 640-19-7
P058 62-74-8
P198 23422-53-9
P197 17702-57-7
P065 628-86-4
P059 76-44-8
P062 757-58-4
P116 79-19-6
P068 60-34-4
P063 74-90-8
P063 74-90-8
P096 7803-51-2
P060 465-73-6
P192 119-38-0
P202 64-00-6
P007 2763-96-4
P196 15339-36-3

-S,S')-,
P196 15339-36-3
P092 62-38-4
P065 628-86-4
P082 62-75-9
P064 624-83-9
P016 542-88-1
P112 509-14-8
P118 75-70-7
P198 23422-53-9
[3-[[(methylamino)-carbonyl]oxy]
phenyl]-, monohydrochloride.
P197 17702-57-7
methyl-4-[[methylamino)carb onyl]oxy]
phenyl]-
P050 115-29-7

pen,6,7,8,9,10,10 -hexachloro-
1,5,5a,6,9,9a-hexahydro-, 3-oxide
P059 76-44-8
heptachloro- 3a,4,7,7a-tetrahydro-
P199 2032-65-7
P066 16752-77-5
P068 60-34-4
P064 624-83-9
P069 75-86-5
P071 298-00-0
P190 1129-41-5
P128 315-8-4
P072 86-88-4
P073 13463-39-3
P074 557-19-7
P075
P076 10102-43-9
P077 100-01-6
P078 10102-44-0
P076 10102-43-9
P078 10102-44-0
P081 55-63-0
P082 62-75-9
P084 4549-40-0
P085 152-16-9
P087 20816-12-0
P087 20816-12-0
P088 145-73-3
dicarboylic acid
P194 23135-22-0
P089 56-38-2
P034 131-89-5
P048 51-28-5
P047
P020 88-85-7
P009 131-74-8

P128 315-18-4
methylcarbamate (ester).
P199 2032-65-7
methylcarbamate
P202 64-00-6
carbamate.
P201 2631-37-0
methyl carbamate
P092 62-38-4
P093 103-85-5
P094 298-02-2
P095 75-44-5
P096 7803-51-2
P041 311-45-5
P039 298-04-4

S-[2-(ethylthio)ethyl] ester
P094 298-02-2
S- [(ethylthio)methyl] ester
P044 60-51-5
S-[2 -(methylamino)-2-oxoethyl] ester
P043 55-91-4
methylethyl) ester
P089 56-38-2
(4-nitrophenyl) ester
P040 297-97-2
O-pyrazinyl ester
P097 52-85-7
no) sulfonyl]phenyl] O,O-dimethyl ester
P071 298-00-0

0-(4-nitrophenyl) ester
P204 57-47-6
P188 57-64-7
P110 78-00-2
P098 151-50-8
P099 506-61-6
P201 2631-37-0
P070 116-06-3
0- [(methylamino)carbonyl]oxime
P203 1646-88-4
O-[(methylamino)carbonyl] oxime.
P101 107-12-0
P027 542-76-7
P069 75-86-5
P081 55-63-0
P017 598-31-2
P102 107-19-7
P003 107-02-8
P005 107-18-6
P067 75-55-8
P102 107-19-7
P008 504-24-5
P075 54-11-5
pyrrolidinyl)-, (S) and salts
P204 57-47-6
hexahydro-1,3a,8-trimethyl-,
methylcarbamate (ester), (3aS-cis)-.
P114 12039-52-0
P103 630-10-4
P104 506-64-9
P105 26628-22-8
P106 143-33-9
P108
P018 357-57-3
P108
P115 7446-18-6
P109 3689-24-5
P110 78-00-2
P111 107-49-3
P112 509-14-8
P062 757-58-4
P113 1314-32-5
P113 1314-32-5
P114 12039-52-0
P115 7446-18-6
P109 3689-24-5
P045 39196-18-4
P049 541-53-7
[(H
P014 108-98-5
P116 79-19-6
P026 5344-82-1
P072 86-88-4
P093 103-85-5
P185 26419-73-8
P123 8001-35-2
P118 75-70-7
P119 7803-55-6
P120 1314-62-1
P120 1314-62-1P084 4549-40-0 (continued)