CCLME.ORG - 40 CFR PART 414—ORGANIC CHEMICALS PLASTICS AND SYNTHETIC FIBERS
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(continued) so must not exceed the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentrations in the following table.

(b) Any new source that does not use end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with §414.101 of this part, and also must not exceed the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentrations in the following table.



------------------------------------------------------------------------
NSPS \1\
---------------------
Maximum
Effluent characteristics Maximum for
for any monthly
one day average
------------------------------------------------------------------------
BOD5.............................................. 92 34
TSS............................................... 159 49
pH................................................ (\2\) (\2\)
------------------------------------------------------------------------
\1\ All units except pH are milligrams per liter.
\2\ Within the range of 6.0 to 9.0 at all times.


§ 414.75 Pretreatment standards for existing sources (PSES).
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Except as provided in 40 CFR 403.7 and 403.13, any existing source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve discharges in accordance with §414.111.

[58 FR 36892, July 9, 1993]

§ 414.76 Pretreatment standards for new sources (PSNS).
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Except as provided in 40 CFR 403.7 any new source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve discharges in accordance with §414.111.

[58 FR 36892, July 9, 1993]

Subpart H—Specialty Organic Chemicals
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§ 414.80 Applicability; description of the specialty organic chemicals subcategory.
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The provisions of this subpart are applicable to the process wastewater discharges resulting from the manufacture of all SIC 2865 and 2869 organic chemicals and organic chemical groups which are not defined as commodity or bulk organic chemicals in §§414.60 and 414.70, respectively.

§ 414.81 Effluent limitations representing the degree of effluent reduction attainable by the application of the best practicable control technology currently available (BPT).
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Except as provided in 40 CFR 125.30 through 125.32, and in 40 CFR 414.11(i) for point sources with production in two or more subcategories, any existing point source subject to this subpart must achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentration listed in the following table.



------------------------------------------------------------------------
BPT effluent
limitations \1\
---------------------
Effluent characteristics Maximum
Maximum for
for any monthly
one day average
------------------------------------------------------------------------
BOD5.............................................. 120 45
TSS............................................... 183 57
pH................................................ (\2\) (\2\)
------------------------------------------------------------------------
\1\ All units except pH are milligrams per liter.
\2\ Within the range of 6.0 to 9.0 at all times.


[52 FR 42568, Nov. 5, 1987, as amended at 57 FR 41844, Sept. 11, 1992]

§ 414.82 Effluent limitations representing the degree of effluent reduction attainable by the application of the best conventional pollutant control technology (BCT). [Reserved]
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§ 414.83 Effluent limitations representing the degree of effluent reduction attainable by the application of the best available technology economically achievable (BAT).
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(a) The Agency has determined that for existing point sources whose total OCPSF production defined by §414.11 is less than or equal to five (5) million pounds of OCPSF products per year, the BPT level of treatment is the best available technology economically achievable. Accordingly, the Agency is not promulgating more stringent BAT limitations for these point sources.

(b) Except as provided in paragraph (a) of this section and in 40 CFR 125.30 through 125.32, any existing point source that uses end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with §414.91 of this part.

(c) Except as provided in paragraph (a) of this section and in 40 CFR 125.30 through 125.32, any existing point source that does not use end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with §414.101 of this part.

§ 414.84 New source performance standards (NSPS).
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(a) Any new source that uses end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with §414.9 of this part, and also must not exceed the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentrations in the following table.

(b) Any new source that does not use end-of-pipe biological treatment and is subject to this subpart must achieve discharges in accordance with §414.101 of this part, and also must not exceed the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentrations in the following table.



------------------------------------------------------------------------
NSPS \1\
---------------------
Maximum
Effluent characteristics Maximum for
for any monthly
one day average
------------------------------------------------------------------------
BOD5.............................................. 120 45
TSS............................................... 183 57
pH................................................ (\2\) (\2\)
------------------------------------------------------------------------
\1\ All units except pH are milligrams per liter.
\2\ Within the range of 6.0 to 9.0 at all times.


§ 414.85 Pretreatment standards for existing sources (PSES).
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Except as provided in 40 CFR 403.7 and 403.13, any existing source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve discharges in accordance with §414.111.

[58 FR 36892, July 9, 1993]

§ 414.86 Pretreatment standards for new sources (PSNS).
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Except as provided in 40 CFR 403.7 any new source subject to this subpart which introduces pollutants into a publicly owned treatment works must comply with 40 CFR part 403 and achieve discharges in accordance with §414.111.

[58 FR 36892, July 9, 1993]

Subpart I—Direct Discharge Point Sources That Use End-of-Pipe Biological Treatment
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§ 414.90 Applicability; description of the subcategory of direct discharge point sources that use end-of-pipe biological treatment.
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The provisions of this subpart are applicable to the process wastewater discharges resulting from the manufacture of the OCPSF products and product groups defined by §414.11 from any point source that uses end-of-pipe biological treatment or installs end-of-pipe biological treatment to comply with BPT effluent limitations.

§ 414.91 Toxic pollutant effluent limitations and standards for direct discharge point sources that use end-of-pipe biological treatment.
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(a) Any point source subject to this subpart must achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentrations in the following table.

(b) In the case of chromium, copper, lead, nickel, zinc, and total cyanide, the discharge quantity (mass) shall be determined by multiplying the concentrations listed in the following table for these pollutants times the flow from metal-bearing waste streams for the metals and times the flow from cyanide bearing waste streams for total cyanide. The metal-bearing waste streams and cyanide-bearing waste streams are defined as those waste streams listed in Appendix A of this part, plus any additional OCPSF process wastewater streams identified by the permitting authority on a case-by-case basis as metal or cyanide bearing based upon a determination that such streams contain significant amounts of the pollutants identified above. Any such streams designated as metal or cyanide bearing must be treated independently of other metal or cyanide bearing waste streams unless the permitting authority determines that the combination of such streams, prior to treatment, with the Appendix A waste streams will result in substantial reduction of these pollutants. This determination must be based upon a review of relevant engineering, production, and sampling and analysis information.



------------------------------------------------------------------------
Effluent limitations
BAT and NSPS \1\
---------------------
Effluent characteristics Maximum
Maximum for any
for any monthly
one day average
------------------------------------------------------------------------
Acenaphthene...................................... 59 22
Acenaphthylene.................................... 59 22
Acrylonitrile..................................... 242 96
Anthracene........................................ 59 22
Benzene........................................... 136 37
Benzo(a)anthracene................................ 59 22
3,4-Benzofluoranthene............................. 61 23
Benzo(k)fluoranthene.............................. 59 22
Benzo(a)pyrene.................................... 61 23
Bis(2-ethylhexyl) phthalate....................... 279 103
Carbon Tetrachloride.............................. 38 18
Chlorobenzene..................................... 28 15
Chloroethane...................................... 268 104
Chloroform........................................ 46 21
2-Chlorophenol.................................... 98 31
Chrysene.......................................... 59 22
Di-n-butyl phthalate.............................. 57 27
1,2-Dichlorobenzene............................... 163 77
1,3-Dichlorobenzene............................... 44 31
1,4-Dichlorobenzene............................... 28 15
1,1-Dichloroethane................................ 59 22
1,2-Dichloroethane................................ 211 68
1,1-Dichloroethylene.............................. 25 16
1,2-trans-Dichloroethylene........................ 54 21
2,4-Dichlorophenol................................ 112 39
1,2-Dichloropropane............................... 230 153
1,3-Dichloropropylene............................. 44 29
Diethyl phthalate................................. 203 81
2,4-Dimethylphenol................................ 36 18
Dimethyl phthalate................................ 47 19
4,6-Dinitro-o-cresol.............................. 277 78
2,4-Dinitrophenol................................. 123 71
2,4-Dinitrotoluene................................ 285 113
2,6-Dinitrotoluene................................ 641 255
Ethylbenzene...................................... 108 32
Fluoranthene...................................... 68 25
Fluorene.......................................... 59 22
Hexachlorobenzene................................. 28 15
Hexachlorobutadiene............................... 49 20
Hexachloroethane.................................. 54 21
Methyl Chloride................................... 190 86
Methylene Chloride................................ 89 40
Naphthalene....................................... 59 22
Nitrobenzene...................................... 68 27
2-Nitrophenol..................................... 69 41
4-Nitrophenol..................................... 124 72
Phenanthrene...................................... 59 22
Phenol............................................ 26 15
Pyrene............................................ 67 25
Tetrachloroethylene............................... 56 22
Toluene........................................... 80 26
Total Chromium.................................... 2,770 1,110
Total Copper...................................... 3,380 1,450
Total Cyanide..................................... 1,200 420
Total Lead........................................ 690 320
Total Nickel...................................... 3,980 1,690
Total Zinc \2\.................................... 2,610 1,050
1,2,4-Trichlorobenzene............................ 140 68
1,1,1-Trichloroethane............................. 54 21
1,1,2-Trichloroethane............................. 54 21
Trichloroethylene................................. 54 21
Vinyl Chloride.................................... 268 104
------------------------------------------------------------------------
\1\ All units are micrograms per liter.
\2\ Total Zinc for Rayon Fiber Manufacture that uses the viscose process
and Acrylic Fiber Manufacture that uses the zinc chloride/solvent
process is 6,796 µg/l and 3,325 µg/l for maximum for any
one day and maximum for monthly average, respectively.


[52 FR 42568, Nov. 5, 1987, as amended at 58 FR 36892, July 9, 1993]

Subpart J—Direct Discharge Point Sources That Do Not Use End-of-Pipe Biological Treatment
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§ 414.100 Applicability; description of the subcategory of direct discharge point sources that do not use end-of-pipe biological treatment.
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The provisions of this subpart are applicable to the process wastewater discharges resulting from the manufacture of the OCPSF products and product groups defined by §414.11 from any point source that does not use end-of-pipe biological treatment and does not install end-of-pipe biological treatment to comply with BPT effluent limitations.

§ 414.101 Toxic pollutant effluent limitations and standards for direct discharge point sources that do not use end-of-pipe biological treatment.
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(a)Any point source subject to this subpart must achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentartions in the following table.

(b) In the case of chromium, copper, lead, nickel, zinc, and total cyanide, the discharge quantity (mass) shall be determined by multiplying the concentrations listed in the following table for these pollutants times the flow from metal bearing waste streams for the metals and times the cyanide-bearing waste streams for total cyanide. The metal-bearing waste streams and cyanide-bearing waste streams are defined as those waste streams listed in Appendix A of this part, plus any additional OCPSF process wastewater streams identified by the permitting authority on a case-by-case basis as metal or cyanide bearing based upon a determination that such streams contain significant amounts of the pollutants identified above. Any such streams designated as metal or cyanide bearing must be treated independently of other metal or cyanide bearing waste streams unless the permitting authority determines that the combination of such streams, prior to treatment, with the Appendix A waste streams will result in substantial reduction of these pollutants. This determination must be based upon a review of relevant engineering, production, and sampling and analysis information.



------------------------------------------------------------------------
BAT effluent
limitations and NSPS
\1\
---------------------
Effluent characteristics Maximum
Maximum for
for any monthly
one day average
------------------------------------------------------------------------
Acenaphthene...................................... 47 19
Acenaphthylene.................................... 47 19
Acrylonitrile..................................... 232 94
Anthracene........................................ 47 19
Benzene........................................... 134 57
Benzo(a)anthracene................................ 47 19
3,4-Benzofluoranthene............................. 48 20
Benzo(k)fluoranthene.............................. 47 19
Benzo(a)pyrene.................................... 48 20
Bis(2-ethylhexyl) phthalate....................... 258 95
Carbon Tetrachloride.............................. 380 142
Chlorobenzene..................................... 380 142
Chloroethane...................................... 295 110
Chloroform........................................ 325 111
Chrysene.......................................... 47 19
Di-n-butyl phthalate.............................. 43 20
1,2-Dichlorobenzene............................... 794 196
1,3-Dichlorobenzene............................... 380 142
1,4-Dichlorobenzene............................... 380 142
1,1-Dichloroethane................................ 59 22
1,2-Dichloroethane................................ 574 180
1,1-Dichloroethylene.............................. 60 22
1,2-trans-Dichloroethylene........................ 66 25
1,2-Dichloropropane............................... 794 196
1,3-Dichloropropylene............................. 794 196
Diethyl phthalate................................. 113 46
2,4-Dimethylphenol................................ 47 19
Dimethyl phthalate................................ 47 19
4,6-Dinitro-o-cresol.............................. 277 78
2,4-Dinitrophenol................................. 4,291 1,207
Ethylbenzene...................................... 380 142
Fluoranthene...................................... 54 22
Fluorene.......................................... 47 19
Hexachlorobenzene................................. 794 196
Hexachlorobutadiene............................... 380 142
Hexachloroethane.................................. 794 196
Methyl Chloride................................... 295 110
Methylene Chloride................................ 170 36
Naphthalene....................................... 47 19
Nitrobenzene...................................... 6,402 2,237
2-Nitrophenol..................................... 231 65
4-Nitrophenol..................................... 576 162
Phenanthrene...................................... 47 19
Phenol............................................ 47 19
Pyrene............................................ 48 20
Tetrachloroethylene............................... 164 52
Toluene........................................... 74 28
Total Chromium.................................... 2,770 1,110
Total Copper...................................... 3,380 1,450
Total Cyanide..................................... 1,200 420
Total Lead........................................ 690 320
Total Nickel...................................... 3,980 1,690
Total Zinc \2\.................................... 2,610 1,050
1,2,4-Trichlorobenzene............................ 794 196
1,1,1-Trichloroethane............................. 59 22
1,1,2-Trichloroethane............................. 127 32
Trichloroethylene................................. 69 26
Vinyl Chloride.................................... 172 97
------------------------------------------------------------------------
\1\ All units are micrograms per liter.
\2\ Total Zinc for Rayon Fiber Manufacture that uses the viscose process
and Acrylic Fibers Manufacture that uses the zinc chloride/solvent
process is 6,796 µg/l and 3,325 µg/l for maximum for any
one day and maximum for monthly average, respectively.


[52 FR 42568, Nov. 5, 1987, as amended at 58 FR 36893, July 9, 1993]

Subpart K—Indirect Discharge Point Sources
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Source: 58 FR 36893, July 9, 1993, unless otherwise noted.

§ 414.110 Applicability; description of the subcategory of indirect discharge point sources.
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The provisions of this subpart are applicable to the process wastewater discharges resulting from the manufacture of the OCPSF products and product groups defined by §414.11 from any indirect discharge point source.

§ 414.111 Toxic pollutant standards for indirect discharge point sources.
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(a) Any point source subject to this subpart must achieve discharges not exceeding the quantity (mass) determined by multiplying the process wastewater flow subject to this subpart times the concentration listed in the following table.

(b) In the case of lead, zinc, and total cyanide the discharge quantity (mass) shall be determined by multiplying the concentrations listed in the following table for these pollutants times the flow from metal-bearing waste streams for metals and times the flow from the cyanide-bearing waste streams for total cyanide. The metal-bearing waste streams and cyanide-bearing waste streams are defined as those waste streams listed in Appendix A of this part, plus any additional OCPSF process wastewater streams identified by the control authority on a case-by-case basis as metal or cyanide bearing based upon a determination that such streams contain significant amounts of the pollutants identified above. Any such streams designated as metal or cyanide bearing must be treated independently of other metal or cyanide bearing waste streams unless the control authority determines that the combination of such streams, prior to treatment, with the Appendix A waste streams will result in substantial reduction of these pollutants. This determination must be based upon a review of relevant engineering, production, and sampling and analysis information.



------------------------------------------------------------------------
PSES and PSNS \1\
---------------------
Maximum
Effluent characteristics Maximum for any
for any monthly
one day average
------------------------------------------------------------------------
Acenaphthene...................................... 47 19
Anthracene........................................ 47 19
Benzene........................................... 134 57
Bis(2-ethylhexyl) phthalate....................... 258 95
Carbon Tetrachloride.............................. 380 142
Chlorobenzene..................................... 380 142
Chloroethane...................................... 295 110
Chloroform........................................ 325 111
Di-n-butyl phthalate.............................. 43 20
1,2-Dichlorobenzene............................... 794 196
1,3-Dichlorobenzene............................... 380 142
1,4-Dichlorobenzene............................... 380 142
1,1-Dichloroethane................................ 59 22
1,2-Dichloroethane................................ 574 180
1,1-Dichloroethylene.............................. 60 22
1,2-trans-Dichloroethylene........................ 66 25
1,2-Dichloropropane............................... 794 196
1,3-Dichloropropylene............................. 794 196
Diethyl phthalate................................. 113 46
Dimethyl phthalate................................ 47 19
4,6-Dinitro-o-cresol.............................. 277 78
Ethylbenzene...................................... 380 142
Fluoranthene...................................... 54 22
Fluorene.......................................... 47 19
Hexachlorobenzene................................. 794 196
Hexachlorobutadiene............................... 380 142
Hexachloroethane.................................. 794 196
Methyl Chloride................................... 295 110
Methylene Chloride................................ 170 36
Naphthalene....................................... 47 19
Nitrobenzene...................................... 6,402 2,237
2-Nitrophenol..................................... 231 65
4-Nitrophenol..................................... 576 162
Phenanthrene...................................... 47 19
Pyrene............................................ 48 20
Tetrachloroethylene............................... 164 52
Toluene........................................... 74 28
Total Cyanide..................................... 1,200 420
Total Lead........................................ 690 320
Total Zinc \2\.................................... 2,610 1,050
1,2,4-Trichlorobenzene............................ 794 196
1,1,1-Trichloroethane............................. 59 22
1,1,2-Trichloroethane............................. 127 32
Trichloroethylene................................. 69 26
Vinyl Chloride.................................... 172 97
------------------------------------------------------------------------
\1\ All units are micrograms per liter.
\2\ Total Zinc for Rayon Fiber Manufacture that uses the viscose process
and Acrylic Fiber Manufacture that uses the zinc chloride/solvent
process is 6,796 µg/l and 3,325 µg/l for maximum for any
one day and maximum for monthly average, respectively.


Appendix A to Part 414—Non-Complexed Metal-Bearing Waste Streams and Cyanide-Bearing Waste Streams
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Chromium


Methylhydroabietate/Esterification of hydroabietic acid (rosin) with methanol

Acrylic acid/Oxidation of propylene via acrolein

N-butyl alcohol/Hydrogenation of n-Butyraldehyde, Oxo process

Cyclohexanone/From phenol via cyclohexanol by hydrogenation-dehydrogenation

Fatty amines/Hydrogenation of fatty nitriles (batch)

Helioptropin/Oxidation of isosafrole, chromium catalyst

Isobutanol/Hydrogenation of isobutyraldehyde, Oxo process

Cyclohexyl Mercaptan/Cyclohexanol + Hydrogen sulfide

Ethyl Mercaptan/Ethanol + Hydrogen sulfide

Methanol/H.P. Synthesis from natural gas via synthetic gas

Oxo Alcohols, C7–C11/Carbonation & hydrogenation of C6–C10 Olefins

Polyoxypropylene diamine/Polypropylene glycol + Ammonia

n-Propyl alcohol/Hydrogenation of propionaldehyde, Oxo process

SAN resin/Suspension polymerization

Styrene/Dehydrogenation of ethylbenzene

Styrene/Dehydration of methyl benzyl alcohol (coproduct of propylene oxide)

1-Tetralol, 1-Tetralone mix/Oxidation of tetralin (1,2,3,4-Tetrahydronaphthalene)

3,3,3-Trifluoropropene/Catalyzed hydrogen fluoride exchange with chlorinated propane

Vinyl toluene/Dehydrogenation (thermal) of ethyltoluene

Copper

Methylhydroabietate/Esterification of hydroabietic acid (rosin) with methanol

Acetaldehyde/Oxidation of ethylene with cupric chloride catalyst

Acetic acid/Catalytic oxidation of butane

Acetone/Dehydrogenation of isopropanol

Acrylamide/Catalytic hydration of acrylonitrile

Acrylic acid/Oxidation of propylene via acrolein

Acrylonitrile/Propylene ammoxidation

Adipic acid/Oxidation of cyclohexanol-cyclohexanone mixture

Adipic acid/Oxidation of cyclohexane via cyclohexanol-cyclohexanone mixture

Allynitrile/Allychloride + sodium cyanide

Aniline/Hydrogenation of nitrobenzene

Benzofurans, 2,3-Dihydro-2,2-dimethyl-7-benzofuranol/ from o-Nitrophenol + Methallyl chloride

n-Butyl alcohol/Hydrogenation of n-Butyraldehyde, Oxo process

1,4-Butanediol/Hydrogenation of 1,4-butynediol

Butryolactone/Dehydrogenation of 1,4-butanediol

Caprolactam/From cyclohexane via cyclohexanone and its oxime

Lilian (hydroxydihydrocitronellal)/Hydration and oxidation of citronellol

1,2-Dichloroethane/Oxyhydrochlorination of ethylene

Dialkyldithiocarbamates, metal salts/Dialkylamines + carbon disulfide

2-Ethylhexanol/from n-Butyraldehyde by Aldo condensation and hydrogenation

Fatty amines/Hydrogenation of fatty nitriles (batch)

Geraniol/B-Myrcene + Hydrogen chloride, esterification of geranyl chloride, hydrolysis of geranyl acetate

Furfuryl alcohol/Hydrogenation of furfural

Geranial (Citral)/Oxidation of geraniol (copper catalyst)

Glyoxal/Oxidation of ethylene glycol

Isobutanol/Hydrogenation of isobutyraldehyde, Oxo process

Isopropanol/Catalytic hydrogenation of acetone

2-Mercaptobenzothiazoles, copper salt/2-Mercaptobenzothiazole + copper salt

Methanol/High pressure synthesis from natural gas via synthetic gas

Methanol/Low pressure synthesis from natural gas via synthetic gas

Methyl ethyl ketone/Dehydrogenation of sec-Butanol

Oxo alcohols, C7–C11/Carbonation & hydrogenation of C6–C10 olefins

Phenol/Liquid phase oxidation of benzoic acid

Polyoxyalkylene amines/Polyoxyalkylene glycol + ammonia

Polyphenylene oxide/Solution polymerization of 2,6-xylenol by oxidative coupling (cuprous salt catalyst)

Polyoxypropylene diamine/Polypropylene glycol + Ammonia

Quinaldine (dye intermediate)/Skraup reaction of aniline + crotonaldehyde

Silicones, silicone fluids/Hydrolysis and condensation of chlorosilanes

Silicones, silicone rubbers/Hydrolysis and condensation of chlorosilanes

Silicones, silicone specialties (grease, dispersion agents, defoamers & other products)

Silicones: Silicone resins/Hydrolysis & condensation of methyl, phenyl & vinyl chlorosilanes

Silicones: Silicone fluids/Hydrolysis of chlorosilanes to acyclic & cyclic organosiloxanes

Styrene/Dehydration of a-Methylbenzyl alcohol (coproduct of propylene oxide)

Tetrachloroethylene (perchloroethylene)/Oxyhydrochlorination of tetrachloroethane

Tris(anilino)s-triazine/Cyanuric chloride + aniline + cogeners

Trichloroethylene/Oxyhydrochlorination of tetrachloroethane

Unsaturated polyester resin/Reaction of maleic anhydride + phthalic anhydride + propylene glycol polyester with styrene or methyl methacrylate

Lead

Alkyd resin/Condensation polymerization

Alkyd resins/Condensation polymerization of phthalic anhydride + glycerin + vegetable oil esters

Dialkydithiocarbamates, metal salts/Dialkylamines + carbon disulfide

Thiuram (dimethyldithiocarbamate) hexasulfide/Dimethyldithiocarbamate + sulfur

Triphenylmethane dyes (methyl violet)/Condensation of Formaldehyde + N-Methylaniline + N,N-dimethylaniline, oxidation of reaction product

4,4'-Bis-(N,N-dimethylaniline) carbinol, Michler's hydrol/Oxidation of 4,4'-Methylene-bis(N,N-dimethylaniline) with lead oxide

Naphthenic acid salts

Stearic acid, metal salts/Neutralization with a metallic base

Nickel

Acetates, 7,11-Hexadecadien-1-ol (gossyplure)/Coupling reactions, low pressure hydrogenation, esterification

Acetates, 9-dodecen-1-ol (pheromone)/Coupling reactions, low pressure hydrogenation, esterification

Acrylic acid/oxidation of propylene via acrolein

Acrylonitrile/Propylene ammoxidation

n-Alkanes/Hydrogenation of C6-C22 alpha olefins (ethylene oligomers)

Adiponitrile/Direct cyanation of butadiene

Alkyl amines/Amination of alcohols

4-Aminoacetanilide/Hydrogenation of 4-Nitroacetanilide

BTX/Hydrogenation of olefins (cyclohexenes)

Terphenyls, hydrogenated/Nickel catalyst, hydrogenation of terphenyl

Bisphenol-A, hydrogenated (Biscyclohexanol-A)/Hydrogenation of Bisphenol-A

Butadiene (1,3)/Extractive distillation of C–4 pyrolyzates

n-Butanol/Hydrogenation of n-Butyraldehyde, Oxo process

1,3-Butylene glycol/Hydrogenation of acetaldol

1,4-Butanediol/Hydrogenation of 1,4-butynediol

Butylenes (mixed)/Distillation pf C4 pyrolyzates

4-Chloro-2-aminophenol/Hydrogenation of 4-Chloro-2-nitrophenol

Lilial (hydroxydihydrocitronellal)/Hydration and oxidation of citronellol

Cycloparaffins/Catalytic hydrogenation of aromatics in kerosene solvent

Cyclohexanol/Hydrogenation of phenol, distillation

Cyclohexanone/From phenol via cyclohexanol by hydrogenation-dehydrogenation

Dialkyldithiocarbamates, metal salts/Dialkylamines + carbon disulfide

Ethylamine/Reductive amination of ethanol

Ethylamines (mono, di, tri)/Reductive ammination (ammonia + hydrogen) of ethanol

Isoeugenol, high % trans/Separation of mixed cis & trans isoeugenols

2-Ethylhexanol/from n-Butyraldehyde by Aldol condensation and hydrogenation

Fatty acids, hydrogenated/tallow & coco acids + Hydrogen

Fatty amines/Hydrogenation of fatty nitriles (batch)

Fatty amines/Hydrogenation of tallow & coco nitriles

Glyoxal-urea formaldehyde textile resin/condensation to N-bis(hydroxymethyl) ureas & N,N'-(dihydroxyethyl) ureas

11-hexadecenal/Coupling rxns, low pressure hydrogenation

Hexahydrophthalic anhydride/Condensation of butadiene & maleic anhydride (Diels-Alder reaction) + hydrogenation

Isobutanol/Hydrogenation of isobutyraldehyde, Oxo process

Diisobutyl amine/Ammonolysis of isobutanol

Isopropyl amines (mono, di)/Reductive ammination (Ammonia + Hydrogen) of isopropanol

Linalool/Pyrolysis of 2-Pinanol

Methanol/High pressure synthesis from natural gas via synthetic gas

Methanol/Low pressure sythesis fron natural gas via synthetic gas

Methanol/Butane oxidation

Tris-(hydroxymethyl) methyl amine/Hydrogenation of tris(hydroxymethyl) nitromethane

N-Methyl morpholine/Morpholine + Methanol

N-Ethyl morpholine/Morpholine + Ethanol

2-Methyl-7,8-epoxy octadecane/Coupling reactions, low pressure hydrogenation, epoxidation

Alpha-Olefins/Ethylene oligomer, & Zeigler Cat.

Petroleum hydrocarbon resins, hydrogenated/Hydrogenation of petroleum hydrocarbon resin products

Pinane/Hydrogenation of A-Pinene

2-Pinanol/Reduction of pinane hydroperoxide

Bis-(p-Octylphenol) sulfide, Nickel salt/p-Octylphenol + sulfur chloride (S2C12), neutralize with Nickel base

Piperazine/Reductive amination of ethanol amine (ammonia & hydrogenation, metal catalyst)

N,N-Dimethylpiperazine/Condensation piperazine + formaldehyde, hydrogenation

Polyoxylalkylene amines/Polyoxyalkylene glycol + Ammonia

Polyoxypropylene diamine/Polypropylene glycol + Ammonia

2-Amino-2-methyl-1-propanol/Hydrogenation of 2-Nitro 2-methyl-1-propanol

3-Methoxypropyl amine/Reductive amination of acrylamide with methanol & hydrogen

N-Propylamine/Reductive ammination (ammonia + hydrogen) of n-propanol

Sorbitol/Hydrogenation of sugars

Sulfolane/Condensation butadiene + sulfur dioxide, Hydrogenation

Thionocarbamates, N-Ethyl-o-isopropyl/Isopropyl xanthate + Ethylamine

Toluene diamine (mixture)/Catalytic hydrogenation of dinitrotoluene

Methylated urea-formaldehyde resins (textile)/Methylation of urea-formaldehyde adduct

Methylated urea-formaldehyde glyoxol (textile resin)/Reaction of methylated urea-formaldehyde + glyoxal

Zinc

Methylhydroabietate, diels-alder adducts/Derivatives of abietic esters from rosin

Acrylic resins/Emulsion or solution polymerization to coatings

Acrylic resins (latex)/Emulsion polymerization of acrylonitrile with polybutadiene

Acrylic fibers (85% polyacrylonitrile) by solution polymerization/Wet spinning

Alkyd Resins/Condensation polymerization of phthalic anhydride + glycerin + vegetable oil esters

Benzene/By-product of styrene by ethylbenzene dehydrogenation

Benzene/By-product of vinyl toluene (from ethyltoluene)

n-butyl alcohol/Hydrogenation of n-Butyraldehyde, Oxo process

Coumarin (benz-a-pyrone)/Salicylaldehyde, Oxo process

Cycloparaffins/Catalytic hydrogenation of aromatics in kerosene solvent

Dithiocarbamates, zinc salt/Reaction of zinc oxide + Sodium dithiocarbamates

Dialkyldithiocarbamates, metal salts/Diakylamines + Carbon disulfide

Dithiocarbamates, metal salts/Dithiocarbamic acid + metal oxide

Thiuram (dimethyldithiocarbamate) hexasulfide/Dimethyldithiocarbamate + sulfur

Fluorescent brighteners/Coumarin based

Ethyl acetate/Redox reaction (Tschenko) of acetaldehyde

Ethylbenzene/Benzene alkylation in liquid phase

Ethylbenzyl chloride/Chloromethylation (Hydrogen chloride + formaldehyde, zinc chloride) of ethylbenzene

2-Ethyl hexanol/Aldol condensation-hydrogenation of n-Butyraldehyde

Glyoxal-urea formaldehyde textile resin/Condensation to N-bis (hydroxymethyl) ureas + N,N'-(Dihydroxyethyl) ureas

Isobutanol/Hydrogenation of isobutyraldehyde, Oxo process

Isopropanol/Catalytic hydrogenation of acetone

Methallylidene diacetate/Condensation of 2-Methypropenal + acetic anhydride

Methanol/Low pressure sythesis from natural gas via synthetic gas

Methyl chloride/Hydrochlorination of methanol

Methylethyl ketone/Dehydrogenation of sec-Butanol

Naphthenic acid salts

Nylon

Nylon 6 & 66 copolymers/Polycondensation of Nylon salt + Caprolatam

Nylon 6 fiber/Extrusion (melt spinning)

Oxo alcohols, C12-C15/Hydroformylation & hydrogenation of C11-C14 olefins

Phenolic urethan resins/Phenol + excess formaldehyde + Methylene aniline diisocyanate

Polystyrene (crystal) modified/Polystyrene + sulfonation, chloromethylation and/or amination

Rayon/Viscose process

SAN resin/Emulsion polymerization

Silicones: Silicone rubbers/Hydrolysis and condensation of chlorosilanes

Silicones: Silicone specialties (grease, dispersion agents, defoamers & other products)

Silicones: Silicone resins/Hydrolysis & condensation of methyl, phenyl & vinyl chlorosilanes

Silicones: Silicone fluids/Hydrolysis of chlorosilanes to acyclic & cyclic organosiloxanes

Stearic acid, metal salts/Neutralization with a metallic base

Styrene/Dehydrogenation of ethylbenzene

Styrene-butadiene resin/Emulsion polymerization

Vinyl acetate/Reduction of acetylene + acetic acid

Vinyl toluene/Dehydrogenation (thermal) of ethyltoluene

Xylenes, mixed/By-product vinyl toluene (from ethyltoluene)

Cyanide

Acetone cyanohydrin/Acetone + Hydrogen cyanide

Acetonitrile/By-product of acrylonitrile from propylene by ammoxidation

Acrylic resins/Solution polymerization

Acrylic fiber (85% acrylonitrile)/Suspension polymerization, and wet spinning

Acrylic fiber (85% acrylonitrile)/Solution polymerization, and wet spinning

Acrylonitrile/Ammoxidation of propylene

Adiponitrile/Butadiene + Hydrogen cyanide (direct cyanation)

Allylnitrile/Allyl chloride + Sodium cyanide

Dimethoxybenzaldehyde/Hydroquinone dimethyl ether + Hydrogen cyanide, hydrolysis

Benzyl cyanide/Benzyl chloride + Sodium cyanide

Coal tar products/Distillation of coal tar condensate

Cyanoacetic acid/Chloracetic acid + sodium cyanide

Cyanuric chloride/Catalyzed trimerization of cyanogen chloride

Vat dyes, Indigo paste as Vat Blue 1/Sodamide + potassium N-Phenylglycine, fused with caustic/N-phenylglycine + Aniline + Formaldehyde + Sodium bisulfite, sodium cyanide, hydrolysis with potassium hydroxide

Disperse dyes, Azo and Vat

Ethylenediamine tetraacetic acid/Ethylenediamine + Formaldehyde + Sodium cyanide

Diethylenetriamine pentaacetic acid/Diethylenetriamine + Formaldehyde + Sodium cyanide

N,N'-bis(o-Acetamidophenol)ethylenediamine, ferric complex/ Salicyladehyde + Ethylenediamine + Hydrogen cyanide, hydrolysis to amide

Diethylenetriamine pentaacetic acid, pentasodium salt/Diethylenetriamine pentaacetic acide + caustic

Ethylenediamine tetraacetic acid, metal salts/Ethylenediamine tetraacetic acid + metal bases

Hydroxyethyl ethylenediamine triacetic acid, trisodium salt/ Ethylenediamine + Ethylene oxide + Formaldehyde + Sodium cyanide, hydrolysis

5,5-Dimethyl hyantoin/Acetone + ammonia + carbon dioxide + hydrogen cyanide

Hydrogen cyanide/By-product of acrylonitrile by ammoxidation of propylene

Iminodiacetic acid/Hexamethylene tetraamine + Hydrogen cyanide, hydrolysis of iminoacetonitrile salt

Methionine/Acrolein + Methyl mercaptan, with hydrogen cyanide and ammonium carbonate

Nitrilotriacetic acid/Hexamethylene tetraamine + Hydrogen cyanide, hydrolysis of nitrilotriacetonitrile salt

Picolines, mixed/Condensation of acetaldehyde + formaldehyde + ammonia

Organic pigments, Azo/Diazotization of aniline cogener, coupling to B-Napthol

Pyrimidines, 2-Isopropyl-4-methoxy-/Isobutyronitrile + methanol, ammonia and methylacetoacetate (ring closure)

Pyridine (synthetic)/Condensation of acetaldehyde + ammonia + formaldehyde

Cyanopyridine/Ammoxidation of picoline

Sarcosine (N-Methyl glycine), sodium salt/Hexamethylene tetraamine + Sodium cyanide, hydrolysis

Thiophene acetic acid/Chloromethylation (Hydrogen chloride + Formaldehyde) + Sodium cyanide, hydrolysis

Tris(anilino)S-triazine/Cyanuric chloride + Aniline and its cogeners

Triethylorthoformate/Ethanol + Hydrogen cyanide

Trimethylorthoformate/Methanol + Hydrogen cyanide


[52 FR 42568, Nov. 5, 1987, as amended at 54 FR 27352, June 29, 1989; 55 FR 26692, June 29, 1990; 57 FR 41844, Sept. 11, 1992]

Appendix B to Part 414—Complexed Metal-Bearing Waste Streams
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Chromium


Azo dye intermediates/Substituted diazonium salts + coupling compounds

Vat dyes

Acid dyes

Azo dyes, metallized/Azo dye + metal acetate

Acid dyes, Azo (including metallized)

Organic pigments, miscellaneous lakes and toners

Copper

Disperse dyes

Acid dyes

Direct dyes

Vat dyes

Sulfur dyes

Disperse dye coupler/N-substitution of 2-Amino-4-acetamidoanisole

Azo dyes, metallized/Azo dye + metal acetate

Direct dyes, Azo

Disperse dyes, Azo and Vat

Organic pigment Green 7/Copper phthalocyanine

Organic pigments

Organic pigments/Phthalocyanine pigments

Organic pigments/Copper phthalocyanine (Blue Crude)

Organic pigments, miscellaneous lakes and toners

Lead

Organic pigments, Quinacridines

Organic pigments, Thioindigoids

Tetraethyl lead/Alkyl halide + sodium-lead alloy

Tetramethyl lead/Alkyl halide + sodium-lead alloy

Nickel

Azo dyes, metallized/Azo dye + metal acetate

Zinc

Organic pigments/Azo pigments by diazotization and coupling


[52 FR 42568, Nov. 5, 1987, as amended at 54 FR 27352, June 29, 1989; 57 FR 41844, Sept. 11, 1992]